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For the reaction : AhArr nB, if 'a' mole...

For the reaction : `AhArr nB`, if 'a' mole of A is taken initially and 'x' moles of A get dissociated at equililbrium. What is the value of degree of dissociation?

A

`((x)/(a^(n)))`

B

`ax`

C

`((a)/(x))^(n)`

D

`((x)/(a))`

Text Solution

AI Generated Solution

The correct Answer is:
To find the degree of dissociation for the reaction \( A \rightleftharpoons nB \), we can follow these steps: ### Step 1: Understand the Reaction The reaction indicates that one mole of A dissociates to form n moles of B. ### Step 2: Initial Moles of A We start with 'a' moles of A. This is our initial amount before any dissociation occurs. ### Step 3: Moles Dissociated at Equilibrium Let 'x' be the number of moles of A that dissociate at equilibrium. ### Step 4: Moles of A at Equilibrium At equilibrium, the number of moles of A remaining will be: \[ \text{Moles of A at equilibrium} = a - x \] ### Step 5: Moles of B at Equilibrium According to the stoichiometry of the reaction, for every mole of A that dissociates, n moles of B are formed. Therefore, the number of moles of B formed will be: \[ \text{Moles of B at equilibrium} = n \cdot x \] ### Step 6: Define Degree of Dissociation The degree of dissociation (\( \alpha \)) is defined as the fraction of the initial amount of reactant that has dissociated. It can be expressed mathematically as: \[ \alpha = \frac{\text{Moles of A dissociated}}{\text{Initial moles of A}} = \frac{x}{a} \] ### Step 7: Final Expression Thus, the degree of dissociation (\( \alpha \)) for the reaction is: \[ \alpha = \frac{x}{a} \] ### Conclusion The degree of dissociation is given by the ratio of the moles of A that dissociate (x) to the initial moles of A (a). ---
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