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The dessociation cosntants of acetic aci...

The dessociation cosntants of acetic acid and propionic acid are `1.0 xx 10^(-5)` and `1.0 xx 10^(-6)` respectively. The value of `P^(K_(a))` (propionic acid) - `P^(K_(a))` (Acetic acid) is

A

10

B

`10^(-1)`

C

1

D

`-1.0`

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The correct Answer is:
To solve the problem of finding the difference in pKa values between propionic acid and acetic acid, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the dissociation constants (Ka)**: - For acetic acid (CH₃COOH), the dissociation constant, \( K_a \), is \( 1.0 \times 10^{-5} \). - For propionic acid (C₂H₅COOH), the dissociation constant, \( K_a \), is \( 1.0 \times 10^{-6} \). 2. **Calculate the pKa values**: - The formula for pKa is given by: \[ pK_a = -\log(K_a) \] - For acetic acid: \[ pK_a \text{ (acetic acid)} = -\log(1.0 \times 10^{-5}) = 5 \] - For propionic acid: \[ pK_a \text{ (propionic acid)} = -\log(1.0 \times 10^{-6}) = 6 \] 3. **Find the difference in pKa values**: - Now, we need to find the difference: \[ pK_a \text{ (propionic acid)} - pK_a \text{ (acetic acid)} = 6 - 5 = 1 \] ### Final Answer: The value of \( pK_a \text{ (propionic acid)} - pK_a \text{ (acetic acid)} \) is **1**. ---
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