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TiCl has structure similar as CsCl, the ...

TiCl has structure similar as CsCl, the co-ordination number of `Ti^(+)` will be:

A

4

B

6

C

10

D

8

Text Solution

AI Generated Solution

The correct Answer is:
To determine the coordination number of \( \text{Ti}^+ \) in \( \text{TiCl} \) which has a structure similar to \( \text{CsCl} \), we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Structure**: - The structure of \( \text{TiCl} \) is similar to that of \( \text{CsCl} \). In \( \text{CsCl} \), the \( \text{Cs}^+ \) ions are located at the body center of the cube, while the \( \text{Cl}^- \) ions are located at the corners of the cube. 2. **Identify the Position of Ions**: - In \( \text{TiCl} \), \( \text{Ti}^+ \) will occupy the body center of the cubic unit cell, and \( \text{Cl}^- \) ions will be located at the eight corners of the cube. 3. **Determine Neighboring Ions**: - The coordination number is defined as the number of nearest neighbor atoms surrounding a central atom. In this case, we need to find how many \( \text{Cl}^- \) ions are nearest to the \( \text{Ti}^+ \) ion. 4. **Count the Corner Ions**: - There are 8 corners in a cube, and each corner is occupied by a \( \text{Cl}^- \) ion. Therefore, \( \text{Ti}^+ \) has 8 \( \text{Cl}^- \) ions as its nearest neighbors. 5. **Conclusion**: - The coordination number of \( \text{Ti}^+ \) in \( \text{TiCl} \) is 8. ### Final Answer: The coordination number of \( \text{Ti}^+ \) in \( \text{TiCl} \) is **8**. ---
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