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(a) CH3 CONH2 +KOH +Br2 (b ) CH3 ...

` (a) CH_3 CONH_2 +KOH +Br_2 `
`(b ) CH_3 COOH + ` soda lime
` (c ) CH_3 COOAg +Br _2 `
All the three reactions show similarilty in :

A

Descending of carbon atoms

B

Ascending of carbon atoms

C

both of (1) and (2)

D

None of the above

Text Solution

AI Generated Solution

The correct Answer is:
To analyze the reactions provided and identify their similarity, we will break down each reaction step by step. ### Reaction (a): CH₃CONH₂ + KOH + Br₂ 1. **Identify the reactants**: We have an amide (CH₃CONH₂), a strong base (KOH), and bromine (Br₂). 2. **Reaction type**: This is a Hofmann degradation reaction. The amide reacts with KOH and Br₂. 3. **Products formation**: The reaction leads to the formation of methylamine (CH₃NH₂) and potassium carbonate (K₂CO₃), along with water (H₂O). 4. **Carbon atom count**: The starting material (CH₃CONH₂) has 2 carbon atoms, and the product (CH₃NH₂) has 1 carbon atom. Thus, there is a decrease of 1 carbon atom. ### Reaction (b): CH₃COOH + Soda Lime 1. **Identify the reactants**: We have acetic acid (CH₃COOH) and soda lime (a mixture of NaOH and CaO). 2. **Reaction type**: This is a decarboxylation reaction. 3. **Products formation**: The acetic acid reacts with soda lime to produce methane (CH₄) and sodium carbonate (Na₂CO₃). 4. **Carbon atom count**: The starting material (CH₃COOH) has 2 carbon atoms, and the product (CH₄) has 1 carbon atom. Thus, there is a decrease of 1 carbon atom. ### Reaction (c): CH₃COOAg + Br₂ 1. **Identify the reactants**: We have silver acetate (CH₃COOAg) and bromine (Br₂). 2. **Reaction type**: This is a reaction of silver salts with bromine, leading to the cleavage of the acetate group. 3. **Products formation**: The reaction produces bromoethane (CH₃Br) and carbon dioxide (CO₂). 4. **Carbon atom count**: The starting material (CH₃COOAg) has 2 carbon atoms, and the product (CH₃Br) has 1 carbon atom. Thus, there is a decrease of 1 carbon atom. ### Summary of Similarity In all three reactions, the number of carbon atoms decreases from the reactants to the products. Each reaction starts with a compound containing 2 carbon atoms and ends with a product that contains only 1 carbon atom. ### Final Conclusion The similarity in all three reactions is that they all show a **decrease in the number of carbon atoms**. ---
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