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[A] + [B ] to C2 H5 NH CONHC2 H5 ...

`[A] + [B ] to C_2 H_5 NH CONHC_2 H_5 `
`{:( (a ) COCl_2 , (b ) ALCl_3),(( c ) C_2 H_5 NH_2 , (d) CH_2 Br_2 ):}`
here , [A] & [B] are

A

a,b

B

b,c

C

c,d

D

a,c

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to identify compounds [A] and [B] that react to form the product C₂H₅NHCONHC₂H₅. The product is an amide, which suggests that one of the reactants must be an acyl chloride (or similar compound) and the other must be an amine. ### Step-by-Step Solution: 1. **Identify the Product Structure**: The product C₂H₅NHCONHC₂H₅ indicates that it contains an amide functional group (C=O attached to NH). The structure can be broken down as follows: - C₂H₅NH- (ethylamine) - CO (carbonyl group) - NH (amide linkage) - C₂H₅ (another ethyl group) 2. **Determine the Reactants**: To form an amide, we typically need: - An acyl chloride (which provides the carbonyl group) - An amine (which provides the nitrogen) 3. **Analyze the Given Options**: We have four options: - (a) COCl₂ (which is an acyl chloride) - (b) AlCl₃ (not relevant for amide formation) - (c) C₂H₅NH₂ (which is ethylamine) - (d) CH₂Br₂ (not relevant for amide formation) 4. **Select the Correct Reactants**: - From the analysis, we can see that: - [A] = COCl₂ (acyl chloride) - [B] = C₂H₅NH₂ (ethylamine) 5. **Reaction Mechanism**: The reaction proceeds as follows: - The nitrogen in ethylamine (B) acts as a nucleophile and attacks the carbonyl carbon in the acyl chloride (A). - This results in the formation of an intermediate where the chlorine atom leaves, leading to the formation of the amide C₂H₅NHCONHC₂H₅. ### Conclusion: Thus, the correct identification of [A] and [B] is: - [A] = COCl₂ - [B] = C₂H₅NH₂
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