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Ph CH(3) overset( NBS ) to (1) overse...

`Ph CH_(3) overset( NBS ) to (1) overset( CN^(-))to (2) ` the product (2) in the sequence is :

A

B

C

D

Text Solution

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The correct Answer is:
To solve the problem step by step, we will analyze the reactions involving phenyl with a methyl group (Ph-CH₃) first with N-bromo-succinimide (NBS) and then with the cyanide ion (CN⁻). ### Step 1: Reaction of Ph-CH₃ with NBS 1. **Identify the starting compound**: The starting compound is toluene (Ph-CH₃). 2. **Understand the role of NBS**: NBS is used for allylic bromination, which involves the formation of a free radical. 3. **Mechanism of reaction**: - When toluene reacts with NBS, a bromine radical is generated. - The bromine radical abstracts an allylic hydrogen (the hydrogen on the carbon adjacent to the methyl group). - This forms a free radical on the carbon adjacent to the methyl group, which can stabilize through resonance. 4. **Formation of Product 1**: The bromine radical then adds to the carbon where the free radical is formed, resulting in the product: - **Product 1**: Benzyl bromide (Ph-CH₂Br). ### Step 2: Reaction of Product 1 with CN⁻ 1. **Identify Product 1**: The product from the first reaction is benzyl bromide (Ph-CH₂Br). 2. **Understand the role of CN⁻**: The cyanide ion (CN⁻) is a good nucleophile. 3. **Mechanism of reaction**: - The cyanide ion will attack the carbon atom that is bonded to the bromine in benzyl bromide. - The bromine atom is a good leaving group and will leave as bromide ion (Br⁻). 4. **Formation of Product 2**: The nucleophilic attack by CN⁻ leads to the formation of: - **Product 2**: Benzyl cyanide (Ph-CH₂CN). ### Final Products - **Product 1**: Benzyl bromide (Ph-CH₂Br) - **Product 2**: Benzyl cyanide (Ph-CH₂CN) ### Summary The final product (2) in the sequence is benzyl cyanide (Ph-CH₂CN). ---
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