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C(6) H5 NH2 overset(CH3 -CH=C=CH2 //H^...

`C_(6) H_5 NH_2 overset(CH_3 -CH=C=CH_2 //H^(+) )to A,` compound 'A' will be

A

para-isopropyl aniline

B

ortho-isopropyl aniline

C

orthop-n-propylaniline

D

reaction does not occur

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to analyze the reaction of aniline (C₆H₅NH₂) with the given reagent (CH₃-CH=CH₂ in the presence of H⁺). ### Step-by-step Solution: 1. **Identify the Reactants**: - The reactant is aniline (C₆H₅NH₂), which is an aromatic amine. - The other reactant is CH₃-CH=CH₂, which is an allyl group, and H⁺ indicates an acidic condition. 2. **Protonation of Aniline**: - Under acidic conditions (presence of H⁺), the lone pair of electrons on the nitrogen atom of aniline can be protonated. - This leads to the formation of an anilinium ion (C₆H₅NH₃⁺). 3. **Formation of Anilinium Ion**: - The reaction can be represented as: \[ C₆H₅NH₂ + H^+ \rightarrow C₆H₅NH₃^+ \] - The anilinium ion is a positively charged species where the nitrogen is bonded to three hydrogen atoms and has a positive charge. 4. **Deactivation of the Aromatic Ring**: - The formation of the anilinium ion deactivates the aromatic ring towards electrophilic substitution reactions because the positive charge on nitrogen withdraws electron density from the ring. - This means that the aromatic ring is less reactive towards further electrophilic attack. 5. **Conclusion**: - Since the anilinium ion is formed and the aromatic ring is deactivated, no further reaction occurs with the allyl group (CH₃-CH=CH₂). - Therefore, the final compound A is simply the anilinium ion, and no substitution or addition reaction occurs. ### Final Answer: The compound A will be the anilinium ion (C₆H₅NH₃⁺), and no further reaction occurs.
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