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A gaseous mixture containing equal mole ...

A gaseous mixture containing equal mole sof `H_(2),O_(2)` and He is subjected to series of effusion steps. The composition (by moles) of effused mixture after 4 effusion steps is `x:1:y` rspectively. Then find the value of `((x)/(y)).`

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To solve the problem, we need to analyze the effusion of the gaseous mixture containing equal moles of \( H_2 \), \( O_2 \), and \( He \). We will use Graham's law of effusion, which states that the rate of effusion of a gas is inversely proportional to the square root of its molar mass. ### Step-by-Step Solution: 1. **Identify Molar Masses**: - Molar mass of \( H_2 \) = 2 g/mol - Molar mass of \( O_2 \) = 32 g/mol - Molar mass of \( He \) = 4 g/mol 2. **Calculate the Rate of Effusion**: According to Graham's law, the rate of effusion \( R \) is given by: \[ R \propto \frac{1}{\sqrt{M}} \] where \( M \) is the molar mass. 3. **Calculate Ratios for Each Gas**: - For \( H_2 \) and \( O_2 \): \[ \frac{R_{H_2}}{R_{O_2}} = \frac{\sqrt{M_{O_2}}}{\sqrt{M_{H_2}}} = \frac{\sqrt{32}}{\sqrt{2}} = \frac{4}{1} \quad \text{(Ratio of rates)} \] - For \( O_2 \) and \( He \): \[ \frac{R_{O_2}}{R_{He}} = \frac{\sqrt{M_{He}}}{\sqrt{M_{O_2}}} = \frac{\sqrt{4}}{\sqrt{32}} = \frac{2}{4} = \frac{1}{2} \quad \text{(Ratio of rates)} \] 4. **Apply Effusion Steps**: Since we are considering 4 effusion steps, we raise the ratios to the power of the number of steps: - For \( H_2 \) to \( O_2 \): \[ \left(\frac{R_{H_2}}{R_{O_2}}\right)^4 = \left(4\right)^4 = 256 \] - For \( O_2 \) to \( He \): \[ \left(\frac{R_{O_2}}{R_{He}}\right)^4 = \left(\frac{1}{2}\right)^4 = \frac{1}{16} \] 5. **Determine the Composition After Effusion**: Let the initial moles of \( H_2 \), \( O_2 \), and \( He \) be equal, say \( n \) moles each. After 4 effusion steps, the remaining moles will be: - Moles of \( H_2 \) = \( n \times 256 \) - Moles of \( O_2 \) = \( n \) - Moles of \( He \) = \( n \times \frac{1}{16} \) 6. **Express the Final Composition**: The final composition by moles can be expressed as: \[ H_2 : O_2 : He = 256n : n : \frac{n}{16} \] Simplifying this gives: \[ 256 : 1 : \frac{1}{16} \] 7. **Find the Value of \( \frac{x}{y} \)**: From the composition \( 256 : 1 : \frac{1}{16} \), we set: - \( x = 256 \) - \( y = \frac{1}{16} \) Therefore: \[ \frac{x}{y} = \frac{256}{\frac{1}{16}} = 256 \times 16 = 4096 \] ### Final Answer: The value of \( \frac{x}{y} \) is \( 4096 \).

To solve the problem, we need to analyze the effusion of the gaseous mixture containing equal moles of \( H_2 \), \( O_2 \), and \( He \). We will use Graham's law of effusion, which states that the rate of effusion of a gas is inversely proportional to the square root of its molar mass. ### Step-by-Step Solution: 1. **Identify Molar Masses**: - Molar mass of \( H_2 \) = 2 g/mol - Molar mass of \( O_2 \) = 32 g/mol - Molar mass of \( He \) = 4 g/mol ...
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