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What is lanthanoid contraction ? What ar...

What is lanthanoid contraction ? What are the consequences of lanthanoid contraction?

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The steady decrease of atomic or ionic size from left to right in lanthanides, as the atomic number increases, is called 'Lanthanide contraction'.
In lanthanides, the differentiating electron enters the (n-2) f sub-shell. Due to their peculiar shapes, f orbitals do not provided proper shielding for the valence electrons from the nuclear attraction. Consequently the atomic or ionic size decreases gradually from left to right in lanthanides.
The decrease in contraction is more regular in `Ln^(+3)` ions than in Ln atom.
Consequences:
(1) Beacuse of the lanthanide contraction, the hardness, m.p, b.p, of the elements increase from Ce to Lu.
(2) There are more similarities between 4d and 5d series of elements, then between 3d and 4d series. The main reason is, 'lanthanide contraction'.
(3) The effect of lanthanide contraction is felt even in the post lanthanides. As a result, atomic sizes in the pairs of elements `Zr//Hf , Nb//Ts, Mo//W` are the same. So these pairs of elements possess similar properties. Zr and Hf resemble each other so much that their isolation is a quite difficult process.
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VGS PUBLICATION-BRILLIANT-CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES -Long Answer Questions
  1. What is lanthanoid contraction ? What are the consequences of lanthano...

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  2. Discuss in detail about the classification of elements by Mendeleeff.

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  3. From a study of properties of neighbouring elements, the properties of...

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  4. Define the mordern periodic law . Discuss the construction of t...

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  5. Discuss the relation between the number of electron filled into the su...

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  6. Write an essay on s, p, d and f-block elements.

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  7. Relate the electronic configuration of elements and their properties i...

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  8. What is a periodic property? How the following properties vary in a gr...

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  9. What is a periodic property? How the following properties vary in a gr...

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  10. What is a periodic property? How the following properties vary in a gr...

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  11. What is a periodic property? How the following properties vary in a gr...

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  12. Write a note on (a) Atomic radius.

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  13. Write a note on (b) Metallic radius.

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  14. Write a note on (c ) Covalent radius.

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  15. Define IE(1) and IE(2). Why is IE(2) > IE(1) for a given atom? Discuss...

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  16. How do the following properties change in group - 1 and in the third p...

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  17. How do the following properties change in group - 1 and in the third p...

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  18. How do the following properties change in group - 1 and in the third p...

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  19. How do the following properties change in group - 1 and in the third p...

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  20. Define electron gain enthalpy. How it varies in a group and in a perio...

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  21. What is electronegativity?

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