Home
Class 12
CHEMISTRY
What is lanthanoid contraction ? What ar...

What is lanthanoid contraction ? What are the consequences of lanthanoid contraction?

Text Solution

Verified by Experts

The steady decrease of atomic or ionic size from left to right in lanthanides, as the atomic number increases, is called 'Lanthanide contraction'.
In lanthanides, the differentiating electron enters the (n-2) f sub-shell. Due to their peculiar shapes, f orbitals do not provided proper shielding for the valence electrons from the nuclear attraction. Consequently the atomic or ionic size decreases gradually from left to right in lanthanides.
The decrease in contraction is more regular in `Ln^(+3)` ions than in Ln atom.
Consequences:
(1) Beacuse of the lanthanide contraction, the hardness, m.p, b.p, of the elements increase from Ce to Lu.
(2) There are more similarities between 4d and 5d series of elements, then between 3d and 4d series. The main reason is, 'lanthanide contraction'.
(3) The effect of lanthanide contraction is felt even in the post lanthanides. As a result, atomic sizes in the pairs of elements `Zr//Hf , Nb//Ts, Mo//W` are the same. So these pairs of elements possess similar properties. Zr and Hf resemble each other so much that their isolation is a quite difficult process.
Promotional Banner

Topper's Solved these Questions

  • CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES

    VGS PUBLICATION-BRILLIANT|Exercise Long Answer Questions|24 Videos
  • CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES

    VGS PUBLICATION-BRILLIANT|Exercise Long Answer Questions|24 Videos
  • CHEMICAL EQUILIBRIUM AND ACIDS-BASES

    VGS PUBLICATION-BRILLIANT|Exercise ADDITIONAL QUESTIONS & ANSWERS|8 Videos
  • ENVIRONMENTAL CHEMISTRY

    VGS PUBLICATION-BRILLIANT|Exercise LONG ANSWER QUESTIONS|6 Videos

Similar Questions

Explore conceptually related problems

What is lanthanide contraction? What are its consequences?

What is actinoid contraction ?

What is lanthanide contraction? Give one of its consequences.

Reason of lanthanodi contraction is

What are the consequences of deforestation ?

Lanthanoid contraction implies

What is the consequence of high concentration of auxins?

Which of the following is not a consequence of the Lathanoid contraction ?

VGS PUBLICATION-BRILLIANT-CLASSIFICATION OF ELEMENTS AND PERIODICITY IN PROPERTIES -Short Answer Questions
  1. What is the basic difference between the electron gain enthalpy and el...

    Text Solution

    |

  2. Would you expect IE(1) for two isotopes of the same element to be the ...

    Text Solution

    |

  3. Increasing order of reactivity among group - 1 elements is Li < Na < K...

    Text Solution

    |

  4. Assign the position of the element having outer electronic configurati...

    Text Solution

    |

  5. Assign the position of the element having outer electronic configurati...

    Text Solution

    |

  6. Predict the formulae of the stable binary compounds that would be form...

    Text Solution

    |

  7. Predict the formulae of the stable binary compounds that would be form...

    Text Solution

    |

  8. Predict the formulae of the stable binary compounds that would be form...

    Text Solution

    |

  9. Predict the formulae of the stable binary compounds that would be form...

    Text Solution

    |

  10. Predict the formulae of the stable binary compounds that would be form...

    Text Solution

    |

  11. Predict the formulae of the stable binary compounds that would be form...

    Text Solution

    |

  12. Write a note on the variation of metallic nature in a group and in a p...

    Text Solution

    |

  13. How does the covalent raduis increase in group 7?

    Text Solution

    |

  14. Which element of 3^(rd) period has the highest I.E(1) ? Explain the va...

    Text Solution

    |

  15. What is valency of an element? How does it vary with respect to hydrog...

    Text Solution

    |

  16. What is diagonal relationship? Give a pair of elements having diagonal...

    Text Solution

    |

  17. What is lanthanoid contraction ? What are the consequences of lanthano...

    Text Solution

    |

  18. The first of lithium is 5.41 eV and electron affinity of Cl is -3.61 e...

    Text Solution

    |

  19. How many Cl atoms can you ionize in the process Cl to Cl^(+) + e by th...

    Text Solution

    |

  20. The electron affinity of chlorine is 3.7 eV. How much energy in kcal i...

    Text Solution

    |