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5 g of a polymer of molecular mass 50kg ...

5 g of a polymer of molecular mass 50kg `mol^(-1)` is dissolved in `1dm^(3)` solution. If the density of this solution is 0.96 kg `dm^(-3)` at 300K, the height of solution that will represent this pressure is:

A

28.13 mm

B

20.85 mm

C

26.52 mm

D

24.94 mm

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to calculate the height of the solution that will represent the osmotic pressure generated by dissolving a polymer in the solution. Here’s a step-by-step breakdown of the solution: ### Step 1: Calculate the number of moles of the polymer Given: - Mass of polymer = 5 g - Molecular mass of polymer = 50 kg/mol = 50000 g/mol Using the formula for moles: \[ \text{Number of moles} = \frac{\text{mass}}{\text{molar mass}} = \frac{5 \, \text{g}}{50000 \, \text{g/mol}} = 0.0001 \, \text{mol} \] ### Step 2: Calculate the concentration of the solution The volume of the solution is given as 1 dm³, which is equivalent to 0.001 m³. The concentration (C) in moles per cubic meter (mol/m³) is calculated as: \[ C = \frac{\text{Number of moles}}{\text{Volume in m}^3} = \frac{0.0001 \, \text{mol}}{0.001 \, \text{m}^3} = 0.1 \, \text{mol/m}^3 \] ### Step 3: Calculate the osmotic pressure The formula for osmotic pressure (\(\Pi\)) is given by: \[ \Pi = C \cdot R \cdot T \] Where: - \(R = 8.314 \, \text{J/(mol K)}\) - \(T = 300 \, \text{K}\) Substituting the values: \[ \Pi = 0.1 \, \text{mol/m}^3 \cdot 8.314 \, \text{J/(mol K)} \cdot 300 \, \text{K} = 249.42 \, \text{Pa} \, (\text{or N/m}^2) \] ### Step 4: Convert the density of the solution The density of the solution is given as 0.96 kg/dm³. To convert this to kg/m³: \[ \text{Density} = 0.96 \, \text{kg/dm}^3 = 0.96 \times 1000 \, \text{kg/m}^3 = 960 \, \text{kg/m}^3 \] ### Step 5: Use the hydrostatic pressure formula The hydrostatic pressure formula is given by: \[ \Pi = \rho g h \] Where: - \(\rho = 960 \, \text{kg/m}^3\) - \(g = 9.8 \, \text{m/s}^2\) - \(h = ?\) Rearranging for \(h\): \[ h = \frac{\Pi}{\rho g} = \frac{249.42 \, \text{Pa}}{960 \, \text{kg/m}^3 \cdot 9.8 \, \text{m/s}^2} \] Calculating \(h\): \[ h = \frac{249.42}{960 \cdot 9.8} \approx 0.02652 \, \text{m} \] ### Step 6: Convert height to millimeters To convert meters to millimeters: \[ h = 0.02652 \, \text{m} \times 1000 = 26.52 \, \text{mm} \] ### Final Answer The height of the solution that will represent this pressure is approximately **26.52 mm**.
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