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1% pure ethyl alcohol is added to the ch...

1% pure ethyl alcohol is added to the chloroform used in hospitals because:

A

It enhances the oxidation of chloroform

B

The poisonous gas phosgene is not formed

C

Ethyl alcohol converts phosgene into into diethyl carbonate non-toxic salt

D

It is helpful in producing unconsciousness

Text Solution

AI Generated Solution

The correct Answer is:
To answer the question of why 1% pure ethyl alcohol is added to chloroform used in hospitals, we can break down the reasoning into several steps: ### Step-by-Step Solution: 1. **Identify the Chemical Composition of Chloroform**: - Chloroform is chemically represented as CHCl₃. 2. **Understand the Risks of Chloroform**: - Chloroform can decompose when exposed to sunlight and oxygen, leading to the formation of a toxic compound known as phosgene (COCl₂). 3. **Recognize the Formation of Phosgene**: - The reaction can be summarized as: \[ \text{CHCl}_3 + \frac{1}{2} \text{O}_2 \xrightarrow{\text{sunlight}} \text{COCl}_2 + \text{other products} \] - Phosgene is a poisonous gas and poses health risks. 4. **Role of Ethyl Alcohol**: - Ethyl alcohol (C₂H₅OH) is added to chloroform to prevent the formation of phosgene. When ethyl alcohol is present, it reacts with any formed phosgene to produce diethyl carbonate, which is a non-toxic compound. 5. **Chemical Reaction Involving Ethyl Alcohol**: - The reaction can be represented as: \[ \text{COCl}_2 + 2 \text{C}_2\text{H}_5\text{OH} \rightarrow \text{(C}_2\text{H}_5\text{O)}_2\text{CO} + 2 \text{HCl} \] - This reaction shows that ethyl alcohol effectively converts the harmful phosgene into a harmless substance. 6. **Conclusion**: - The primary reason for adding 1% pure ethyl alcohol to chloroform is to prevent the formation of the toxic gas phosgene and to convert it into diethyl carbonate, which is non-toxic. ### Final Answer: 1% pure ethyl alcohol is added to chloroform used in hospitals to convert any phosgene formed into diethyl carbonate, a non-toxic compound. ---
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