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"CCl"(4) does not give a precipitate wi...

`"CCl"_(4)` does not give a precipitate with `"AgNO"_(3)` . The reason is :

A

Formation of a complex

B

Evolution of `Cl_(2)` gas

C

Chloride ion is not formed

D

`"AgNO"_(3)` does not give Ag ions

Text Solution

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The correct Answer is:
To solve the question of why CCl₄ does not give a precipitate with AgNO₃, we can break it down into a step-by-step explanation: ### Step 1: Understanding the Reaction When CCl₄ (carbon tetrachloride) is mixed with AgNO₃ (silver nitrate), we are looking for the formation of a precipitate, specifically AgCl (silver chloride), which is known to be a white precipitate. **Hint:** Consider what is required for a precipitate to form in a chemical reaction. ### Step 2: Analyzing CCl₄ Structure CCl₄ is a covalent compound. It consists of one carbon atom bonded to four chlorine atoms through covalent bonds. In covalent bonding, atoms share electrons rather than transferring them completely. **Hint:** Recall the nature of covalent bonds and how they differ from ionic bonds. ### Step 3: Valence Electrons in CCl₄ In CCl₄, the carbon atom has 4 valence electrons, and each chlorine atom has 7 valence electrons. The carbon shares one electron with each chlorine atom, resulting in a complete octet for carbon and each chlorine. **Hint:** Think about how electron sharing affects the availability of ions in the solution. ### Step 4: Lack of Chloride Ion Formation Since CCl₄ is covalently bonded, it does not dissociate into ions in solution. This means that no chloride ions (Cl⁻) are produced when CCl₄ is mixed with AgNO₃. The formation of AgCl requires the presence of Cl⁻ ions. **Hint:** Consider what ions are necessary for the formation of a precipitate and whether they are present in the solution. ### Step 5: Conclusion Since there are no chloride ions formed from CCl₄, there can be no reaction with AgNO₃ to produce AgCl. Therefore, no precipitate is formed. **Final Answer:** CCl₄ does not give a precipitate with AgNO₃ because it does not produce chloride ions (Cl⁻) due to its covalent nature. ### Summary of the Reason The reason CCl₄ does not give a precipitate with AgNO₃ is that no chloride ions are formed from CCl₄, which is necessary for the formation of AgCl precipitate.
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