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A overset(OBr^(-))(rarr) "CHBr"(3) the ...

A `overset(OBr^(-))(rarr) "CHBr"_(3)` the compound is :

A

Isopropyl alcohol

B

Isobutyl alcohol

C

Neopentyl alcohol

D

n-Butanol

Text Solution

AI Generated Solution

The correct Answer is:
To determine the compound A that reacts with \( \overset{OBr^{-}}{\rightarrow} CHBr_3 \), we need to identify the type of reaction taking place and the necessary conditions for this reaction. ### Step-by-Step Solution: 1. **Identify the Reaction Type**: The reaction is a Haloform reaction, which typically involves the conversion of a methyl ketone or a compound that can be oxidized to a methyl ketone into a haloform (like chloroform, bromoform, or iodoform) in the presence of a halogen and a base. **Hint**: Recall that Haloform reactions require a methyl ketone structure (C=O with a methyl group). 2. **Determine the Necessary Structure**: For the Haloform reaction to occur, the compound must have a methyl ketone structure, which is characterized by the functional group \( C=O \) adjacent to a \( CH_3 \) group (i.e., \( C(=O)CH_3 \)). **Hint**: Look for compounds that can be oxidized to form a methyl ketone. 3. **Examine the Given Options**: - **Isopropyl Alcohol**: This is a secondary alcohol that can be oxidized to acetone (a methyl ketone). - **Isobutyl Alcohol**: This is a primary alcohol that oxidizes to an aldehyde, which does not have the methyl ketone structure. - **Neopentyl Alcohol**: This is also a primary alcohol that oxidizes to an aldehyde, lacking the methyl ketone structure. - **Normal Butanol**: This is another primary alcohol that oxidizes to an aldehyde, again lacking the methyl ketone structure. **Hint**: Identify which of these compounds can yield a methyl ketone upon oxidation. 4. **Perform the Oxidation**: - **Isopropyl Alcohol**: Oxidizes to acetone \( (CH_3COCH_3) \), which has the required methyl ketone structure. - **Isobutyl Alcohol, Neopentyl Alcohol, and Normal Butanol**: All oxidize to aldehydes, which do not have the methyl ketone structure. **Hint**: Only the compound that can be oxidized to a methyl ketone will participate in the Haloform reaction. 5. **Conclusion**: Since only isopropyl alcohol can be oxidized to form a methyl ketone, it is the only compound that will react with \( OBr^{-} \) to produce \( CHBr_3 \). **Final Answer**: The compound A is **Isopropyl Alcohol**.
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