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In the reaction CH(3)C equiv C^(-)Na^(...

In the reaction
`CH_(3)C equiv C^(-)Na^(+) + (CH_(3))_(2) `CHCl `rarr` Product the product fomed is :

A

4-Methyl-2-pentyne

B

Propyne

C

Propyne and propene

D

None of these

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to analyze the reaction between the sodium salt of an alkyne and 2-chloropropane. Here’s a step-by-step breakdown: ### Step 1: Identify the Reactants The reactants in the reaction are: - Sodium salt of an alkyne: \( CH_3C \equiv C^{-}Na^{+} \) - 2-Chloropropane: \( (CH_3)_2CHCl \) ### Step 2: Understand the Structure of the Reactants 1. **Sodium Salt of Alkyne**: - The structure can be represented as: \[ CH_3-C \equiv C^{-} \quad (with \, Na^{+}) \] - This has a nucleophilic carbon atom (the one with the negative charge). 2. **2-Chloropropane**: - The structure is: \[ CH_3-CH(Cl)-CH_3 \] - The carbon atom attached to chlorine is electrophilic due to the electronegativity of chlorine. ### Step 3: Reaction Mechanism - The nucleophilic carbon from the sodium salt of the alkyne will attack the electrophilic carbon in 2-chloropropane. - This results in the displacement of the chlorine atom (a nucleophilic substitution reaction). ### Step 4: Formation of the Product - The product formed will be an extended alkyne: \[ CH_3-C \equiv C-CH(CH_3)-CH_3 \] - The sodium chloride (NaCl) is released as a byproduct. ### Step 5: Naming the Product 1. **Identify the Longest Carbon Chain**: The longest chain contains 5 carbon atoms. 2. **Number the Chain**: Start numbering from the end nearest to the alkyne functional group: - The numbering will be: 1 (alkyne) - 2 - 3 - 4 - 5. 3. **Identify Substituents**: There is a methyl group at position 4. 4. **IUPAC Name**: The name of the compound will be: - 4-methyl-pent-2-yne. ### Final Answer The product formed from the reaction is **4-methyl-pent-2-yne**. ---
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