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Identify Z in the following series: C...

Identify Z in the following series:
` C_(2) H_(5) I underset("KOH")overset("Alcoholic")(rarr) " X " overset(Br_(2))(rarr) " Y " overset("KCN")(rarr) Z `

A

`CH_(3) - CH_(2) - CN`

B

`CN - CH_(2) - CH_(2) - CN`

C

`Br-CH_(2) - CH_(2) - CN `

D

`Br - CH = CH - CN `

Text Solution

AI Generated Solution

The correct Answer is:
To identify Z in the given series of reactions, we will follow the steps outlined in the question. ### Step 1: Identify the starting compound The starting compound is ethyl iodide, which has the formula \( C_2H_5I \) or \( CH_3CH_2I \). ### Step 2: Reaction with Alcoholic KOH When ethyl iodide reacts with alcoholic potassium hydroxide (KOH), it undergoes a beta elimination reaction (dehydrohalogenation). In this reaction, the iodine atom (I) and a hydrogen atom from the beta carbon are eliminated, resulting in the formation of ethene (X). **Reaction:** \[ CH_3CH_2I \xrightarrow{KOH \, (alcoholic)} CH_2=CH_2 + HI \] ### Step 3: Reaction with Bromine Next, the product ethene (X) reacts with bromine (Br2). This reaction results in the addition of bromine across the double bond, forming a dibromo derivative (Y). **Reaction:** \[ CH_2=CH_2 + Br_2 \rightarrow CH_2Br-CH_2Br \] ### Step 4: Reaction with Potassium Cyanide The dibromo compound (Y) then reacts with potassium cyanide (KCN). In this reaction, the cyanide ion (CN-) acts as a nucleophile and attacks the electrophilic carbon atom bonded to bromine. Since there are two bromine atoms, both can be replaced by cyanide ions, leading to the formation of a dicyano derivative (Z). **Reaction:** \[ CH_2Br-CH_2Br + 2KCN \rightarrow CH_2(CN)-CH_2(CN) + 2KBr \] ### Conclusion The final product Z is a dicyano derivative, specifically 1,2-ethanedicarbonitrile, which can be represented as \( CH_2(CN)-CH_2(CN) \) or \( C_2H_2N_2 \). ### Answer: **Z is 1,2-ethanedicarbonitrile (dicyano derivative).** ---
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