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C(2) H(5) Cl + KCN rarr "X " overset("Hy...

`C_(2) H_(5) Cl` + `KCN` `rarr "X " overset("Hydroysis")(rarr) `Y, 'X' and 'Y' are:

A

`C_(2) H_(6) and C_(2) H_(5)`CN

B

`C_(2)H_(5)`CN and `C_(2)H_(6)`

C

`C_(2)H_(5)`CN and `C_(2)H_(5)CH_(2)NH_(2)`

D

`C_(2)H_(5)`CN and `C_(2)H_(5)`COOH

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question, we need to identify the products 'X' and 'Y' formed from the reaction of ethyl chloride (C₂H₅Cl) with potassium cyanide (KCN), followed by hydrolysis. ### Step 1: Identify the reactants The reactants in this reaction are: - Ethyl chloride (C₂H₅Cl) - Potassium cyanide (KCN) ### Step 2: Understand the reaction mechanism Ethyl chloride contains a chlorine atom that is electronegative. This creates a partial positive charge on the carbon atom, making it an electrophilic center. The cyanide ion (CN⁻) from potassium cyanide acts as a nucleophile due to its partial negative charge. ### Step 3: Nucleophilic substitution reaction When KCN reacts with ethyl chloride, the nucleophile (CN⁻) attacks the electrophilic carbon atom in ethyl chloride, leading to the substitution of the chlorine atom. The reaction can be represented as follows: \[ \text{C}_2\text{H}_5\text{Cl} + \text{KCN} \rightarrow \text{C}_2\text{H}_5\text{CN} + \text{KCl} \] Here, the product formed is propanenitrile (C₂H₅CN), which we will denote as 'X'. ### Step 4: Hydrolysis of the nitrile Next, we perform hydrolysis on the product 'X' (propanenitrile). Hydrolysis of a nitrile typically involves converting it to an amide and then to a carboxylic acid. The reaction can be summarized as follows: 1. Hydrolysis of propanenitrile (C₂H₅CN) leads to propanamide (C₂H₅CONH₂). 2. Further hydrolysis of propanamide results in propanoic acid (C₂H₅COOH). Thus, the final product 'Y' after hydrolysis is propanoic acid. ### Step 5: Summarize the products - Product 'X' is propanenitrile (C₂H₅CN). - Product 'Y' is propanoic acid (C₂H₅COOH). ### Conclusion The final answer is: - X = Propanenitrile (C₂H₅CN) - Y = Propanoic acid (C₂H₅COOH)
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