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For the preparation of alpha -butylene ...

For the preparation of `alpha` -butylene from methyl magnesium chloride, it will be reacted with

A

Propene

B

Propyl chloride

C

3–Chloro propene

D

2–Chloro propene

Text Solution

AI Generated Solution

The correct Answer is:
To prepare alpha-butylene from methyl magnesium chloride, we need to follow a series of steps. Here’s a detailed step-by-step solution: ### Step 1: Understand the Reactants We start with methyl magnesium chloride (CH₃MgBr), which is a Grignard reagent. Grignard reagents are highly reactive and can react with various electrophiles. ### Step 2: Identify the Desired Product The target product is alpha-butylene, which has the structure CH₂=CH-CH₂-CH₃. This indicates that we need a four-carbon chain with a double bond between the first and second carbon atoms. ### Step 3: Choose the Electrophile To form alpha-butylene, we need to react the Grignard reagent with an appropriate electrophile. The electrophile should be a compound that can provide the necessary carbon chain and allow for the formation of a double bond. ### Step 4: Select the Correct Electrophile In this case, we can use 3-chloropropene (CH₂=CH-CH₂Cl) as the electrophile. The structure of 3-chloropropene is CH₂=CH-CH₂Cl, which has three carbons and a chlorine atom attached to the third carbon. ### Step 5: Mechanism of Reaction The reaction occurs via an SN2 mechanism. The nucleophilic carbon (from the methyl group of the Grignard reagent) will attack the carbon atom bonded to the chlorine in 3-chloropropene. This will result in the displacement of the chlorine atom and the formation of a new carbon-carbon bond. ### Step 6: Write the Reaction The reaction can be represented as follows: \[ \text{CH}_3\text{MgBr} + \text{CH}_2=CH-CH_2\text{Cl} \rightarrow \text{CH}_2=CH-CH_2-CH_3 + \text{MgBrCl} \] ### Step 7: Conclusion The product formed from this reaction is alpha-butylene (CH₂=CH-CH₂-CH₃), confirming that the correct electrophile to react with methyl magnesium chloride is 3-chloropropene. ### Final Answer The correct answer is **3-Chloropropene**. ---
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