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What is the final product of the followi...

What is the final product of the following reaction?
`CH_(3) CH = CH_(2) + NBS rarr " A " overset("AgCN")(rarr)`B (Major)

A

`CH_(3)`CH =CHCN

B

`CH_(3) `CH = CHNC

C

`CH_(2) = CHCH_(2)`CN

D

`CH_(2) = CHCH_(2)`NC

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem of determining the final product of the reaction between propene (CH₃CH=CH₂) and NBS followed by AgCN, we will go through the reaction step by step. ### Step 1: Identify the Reactants The initial reactant is propene, which can be represented as: \[ \text{CH}_3\text{CH}=\text{CH}_2 \] ### Step 2: Reaction with NBS NBS (N-Bromosuccinimide) is used for bromination at the allylic position via a free radical mechanism. In propene, the allylic position is the carbon adjacent to the double bond. - The allylic carbon in propene is the carbon that is connected to the double bond. In this case, it is the carbon that is part of the CH₃ group. - The reaction will result in the removal of one hydrogen from the allylic position and the addition of a bromine atom. The product after bromination (let's call it compound A) will be: \[ \text{CH}_2\text{BrCH}=\text{CH}_2 \] This can be rearranged to: \[ \text{CH}_2\text{Br-CH}=\text{CH}_2 \] ### Step 3: Reaction with AgCN Next, we take compound A and react it with AgCN (Silver cyanide). This reaction involves a nucleophilic substitution mechanism. - AgCN does not dissociate into ions, so the nucleophilic attack will be carried out by the nitrogen atom in the cyanide group (CN). - The nitrogen will attack the carbon that is bonded to bromine in the compound A. The product after this reaction (let's call it compound B) will be: \[ \text{CH}_2\text{CN-CH}=\text{CH}_2 \] ### Final Product Thus, the final product B after the reaction with AgCN is: \[ \text{CH}_2\text{=CH-CH}_2\text{CN} \] ### Summary of the Final Product The major product of the reaction sequence is: \[ \text{CH}_2\text{=CH-CH}_2\text{CN} \]
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