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Ehtanol reacts with acetic anhydride to ...

Ehtanol reacts with acetic anhydride to give :

A

Higher alcohol

B

Ether

C

Ester

D

Alkene

Text Solution

AI Generated Solution

The correct Answer is:
To determine what ethanol reacts with acetic anhydride to produce, we can follow these steps: ### Step 1: Identify the Reactants Ethanol (C2H5OH) and acetic anhydride (CH3COOCOCH3) are the two reactants involved in the reaction. **Hint:** Always start by identifying the chemical structures of the reactants involved in the reaction. ### Step 2: Understand the Reaction Type The reaction between ethanol and acetic anhydride is a nucleophilic acyl substitution reaction, where ethanol acts as a nucleophile and acetic anhydride acts as an electrophile. **Hint:** Recognize that nucleophiles donate electron pairs to electrophiles, leading to the formation of new bonds. ### Step 3: Nucleophilic Attack The oxygen atom in ethanol (C2H5OH) has a lone pair of electrons, which allows it to attack the carbonyl carbon of acetic anhydride. This results in the formation of a tetrahedral intermediate. **Hint:** Look for the lone pairs on the nucleophile that allow it to attack the electrophile. ### Step 4: Formation of the Intermediate When ethanol attacks acetic anhydride, a tetrahedral intermediate is formed. This intermediate has a negatively charged oxygen atom and a positively charged oxygen atom. **Hint:** Keep track of the charges during the reaction as they can indicate the stability of intermediates. ### Step 5: Collapse of the Intermediate The tetrahedral intermediate collapses, leading to the expulsion of an acetate ion (CH3COO-) and the formation of ethyl acetate (C2H5OCOCH3). **Hint:** The leaving group is usually a stable ion or molecule that can be expelled from the reaction. ### Step 6: Final Products The final products of the reaction are ethyl acetate (C2H5OCOCH3) and acetic acid (CH3COOH). **Hint:** Always write down the final products clearly to confirm the outcome of the reaction. ### Conclusion Thus, when ethanol reacts with acetic anhydride, the products formed are ethyl acetate and acetic acid. **Final Answer:** Ethanol reacts with acetic anhydride to give ethyl acetate (an ester) and acetic acid. ---
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