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Identify X in the reaction HCHO + CH(3...

Identify X in the reaction ` HCHO + CH_(3)Mgloverset("dry ether")to "Intermediate" overset(H_(2) "O"//H^(+)) to X ` :

A

`CH_(3) OH`

B

`CH_(3) CH_(2) OH`

C

`CH_(3) COCH_(3)`

D

`CH_(3)OCH_(3)`

Text Solution

AI Generated Solution

The correct Answer is:
To identify the compound X in the reaction given, we will follow the steps of the reaction involving formaldehyde (HCHO) and methylmagnesium iodide (CH3MgI) in dry ether, followed by hydrolysis in acidic conditions. ### Step-by-Step Solution: 1. **Identify the Reactants**: - We have formaldehyde (HCHO) and methylmagnesium iodide (CH3MgI). The Grignard reagent (CH3MgI) contains a methyl group (CH3) and a magnesium iodide (MgI) part. 2. **Nucleophilic Addition Reaction**: - The Grignard reagent acts as a nucleophile. The methyl group (CH3-) from CH3MgI attacks the electrophilic carbon of the carbonyl group (C=O) in formaldehyde (HCHO). - This leads to the formation of a tetrahedral intermediate. 3. **Formation of the Intermediate**: - The reaction can be represented as: \[ HCHO + CH3MgI \rightarrow H2C(OH)(CH3)MgI \] - Here, the carbonyl oxygen becomes negatively charged (alkoxide), and the magnesium iodide stabilizes this negative charge. 4. **Hydrolysis of the Intermediate**: - The intermediate formed is then subjected to hydrolysis in the presence of water (H2O) and an acid (H+). - During hydrolysis, the alkoxide (O-) is protonated, and the bond between the carbon and magnesium iodide is cleaved. - This results in the formation of ethanol (ethyl alcohol) and magnesium iodide hydroxide (Mg(OH)I): \[ H2C(OH)(CH3)MgI + H2O \rightarrow CH3CH2OH + Mg(OH)I \] 5. **Final Product (X)**: - The final product X is identified as ethanol (CH3CH2OH). ### Conclusion: Thus, the compound X formed in this reaction is **ethanol (C2H5OH)**.
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