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The missing structures A and B in the r...

The missing structures A and B in the reaction sequence :
`CH_(3) - CH = CH_(2) overset(B_(2)H_(6))to A overset (H_(2)O_(2)+NaOH) to B ` are given by the set :

A

`CH_(3) - CH_(2) - CH_(2) - BH_(2), CH_(3) - CH_(2) - CH_(2) OH`

B

`(CH_(3) - CH_(2)-CH_(2))_(3) B, CH_(3) - CH_(2) - CH_(2)OH`

C

`(CH_(3))_(2) CH - CH_(2) - _(2), CH_(3) - CH(OH) - CH`

D

`(CH_(3) CHCH)_(2) BH, CH_(3)-CH_(2) - CH_(2) OH`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the missing structures A and B in the reaction sequence involving hydroboration oxidation, we will follow these steps: ### Step 1: Identify the starting material The starting material given is **CH₃-CH=CH₂** (propene). This is an alkene that will undergo hydroboration. **Hint:** Remember that alkenes are electron-rich and can react with electrophiles. ### Step 2: Understand the hydroboration reaction The hydroboration reaction involves the addition of **B₂H₆** (diborane) to the alkene. In this reaction, diborane adds across the double bond of the alkene, resulting in the formation of a trialkylborane intermediate. **Hint:** Hydroboration is a syn-addition process, meaning that both the boron and hydrogen add to the same side of the double bond. ### Step 3: Draw the intermediate structure A When **B₂H₆** reacts with propene, it will form an organoborane compound. The boron atom will attach to the less substituted carbon (due to sterics), leading to the formation of **A**: - Structure A: **CH₃-CH₂-CH₂-BH₂** (1-boropropane) **Hint:** The boron atom will bond to the carbon that leads to a more stable carbocation upon further reactions. ### Step 4: Oxidation of the organoborane The next step involves the oxidation of the organoborane with **H₂O₂** (hydrogen peroxide) in the presence of **NaOH**. This reaction converts the boron atom into a hydroxyl group (-OH), replacing the boron with an alcohol functional group. **Hint:** The oxidation step transforms the boron compound into an alcohol, which is a common transformation in organic chemistry. ### Step 5: Draw the final product structure B After the oxidation, the final product **B** will be: - Structure B: **CH₃-CH₂-CH₂-OH** (propan-1-ol) **Hint:** The final product will have the hydroxyl group (-OH) attached to the terminal carbon of the propyl chain. ### Summary of Structures - Structure A: **CH₃-CH₂-CH₂-BH₂** - Structure B: **CH₃-CH₂-CH₂-OH** ### Final Answer The missing structures A and B are: - A: **CH₃-CH₂-CH₂-BH₂** - B: **CH₃-CH₂-CH₂-OH**
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