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The circumference of the 4^(th) bohr orb...

The circumference of the `4^(th)` bohr orbit of hydrogen is 5.32 nm .The wavelenght of electron revolving in the first bohr orbit will be

A

0.133 nm

B

0.3325 nm

C

2.65 nm

D

133 nm

Text Solution

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The correct Answer is:
To find the wavelength of the electron revolving in the first Bohr orbit of hydrogen, we can follow these steps: ### Step 1: Understand the relationship between circumference and radius The circumference of a circular orbit is given by the formula: \[ C = 2\pi r \] where \( r \) is the radius of the orbit. ### Step 2: Use the given circumference of the 4th Bohr orbit We are given that the circumference of the 4th Bohr orbit is 5.32 nm. Therefore, we can write: \[ C_4 = 2\pi r_4 = 5.32 \, \text{nm} \] ### Step 3: Calculate the radius of the 4th Bohr orbit From the circumference formula, we can solve for \( r_4 \): \[ r_4 = \frac{C_4}{2\pi} = \frac{5.32 \, \text{nm}}{2\pi} \] Calculating this gives: \[ r_4 \approx \frac{5.32}{6.2832} \approx 0.847 \, \text{nm} \] ### Step 4: Use the Bohr radius formula to find the radius of the 1st Bohr orbit The radius of the nth Bohr orbit is given by: \[ r_n = r_0 n^2 \] where \( r_0 \) is the radius of the first Bohr orbit (approximately 0.529 Å or 0.0529 nm) and \( n \) is the principal quantum number. For the 4th orbit (n=4): \[ r_4 = r_0 \cdot 4^2 = r_0 \cdot 16 \] ### Step 5: Relate the radius of the 4th orbit to the radius of the 1st orbit We can express \( r_0 \) in terms of \( r_4 \): \[ r_0 = \frac{r_4}{16} \] Substituting \( r_4 \): \[ r_0 = \frac{0.847 \, \text{nm}}{16} \approx 0.0529 \, \text{nm} \] ### Step 6: Calculate the wavelength of the electron in the first Bohr orbit The wavelength \( \lambda \) of the electron can be calculated using the de Broglie wavelength formula: \[ \lambda = \frac{h}{mv} \] However, for Bohr orbits, we can use the relationship: \[ \lambda = \frac{C_1}{n} \] where \( C_1 \) is the circumference of the first orbit. The circumference of the first orbit is: \[ C_1 = 2\pi r_0 \] Substituting \( r_0 \): \[ C_1 = 2\pi (0.0529 \, \text{nm}) \approx 0.331 \, \text{nm} \] Thus, the wavelength of the electron in the first Bohr orbit is: \[ \lambda = C_1 = 0.331 \, \text{nm} \] ### Final Answer The wavelength of the electron revolving in the first Bohr orbit is approximately **0.331 nm**. ---
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