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The product obtained by the reaction of ...

The product obtained by the reaction of silver propanoate with bromine in carbon tetrachloride solution is:

A

Bromoethane

B

Silver-3-bromopropanoate

C

Ethanoyl bromide

D

None of the above

Text Solution

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The correct Answer is:
To determine the product obtained by the reaction of silver propanoate with bromine in carbon tetrachloride (CCl4), we can follow these steps: ### Step 1: Identify the Reactants The reactants in this reaction are: - Silver propanoate (CH3CH2COOAg) - Bromine (Br2) - Solvent: Carbon tetrachloride (CCl4) ### Step 2: Understand the Reaction Type This reaction is a type of halogenation involving a silver salt of a carboxylic acid. Specifically, it follows the Hunsdiecker reaction mechanism, which involves the formation of an alkyl halide from the silver salt of a carboxylic acid. ### Step 3: Analyze the Structure of Silver Propanoate The structure of silver propanoate can be represented as: - CH3-CH2-C(=O)O^- Ag^+ This indicates that it has a three-carbon chain (propanoate) with a silver ion. ### Step 4: Reaction Mechanism In the presence of bromine and CCl4, the following steps occur: 1. The Br2 molecule undergoes homolytic cleavage to generate two bromine radicals (Br·). 2. The silver propanoate reacts with Br2, leading to the formation of a radical intermediate and the release of carbon dioxide (CO2). 3. The alkyl radical (CH3CH2·) formed from the propanoate will then react with a bromine radical to form bromoethane (CH3CH2Br). ### Step 5: Determine the Product From the above steps, the product formed is: - Bromoethane (CH3CH2Br) ### Step 6: Byproducts In addition to bromoethane, the reaction also produces: - Silver bromide (AgBr) - Carbon dioxide (CO2) ### Conclusion The final product obtained from the reaction of silver propanoate with bromine in CCl4 is bromoethane (CH3CH2Br). ### Summary of the Final Product - **Product**: Bromoethane (CH3CH2Br) - **Byproducts**: Silver bromide (AgBr) and carbon dioxide (CO2) ---
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