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Best reductant reduces chloroform to:...

Best reductant reduces chloroform to:

A

`C_(2)H_(4)`

B

`CH_(4)`

C

`C_(2)H_(2)`

D

`C_(2)H_(6)`

Text Solution

AI Generated Solution

The correct Answer is:
To determine the best reductant that reduces chloroform (CHCl3) to its lowest oxidation state, we can follow these steps: ### Step 1: Determine the oxidation state of carbon in chloroform (CHCl3). - The oxidation state of carbon (C) can be calculated using the formula: \[ \text{Oxidation state of C} = x + 1 + 3(-1) = 0 \] where \(x\) is the oxidation state of carbon. Simplifying this gives: \[ x - 2 = 0 \implies x = +2 \] - Therefore, the oxidation state of carbon in chloroform is +2. ### Step 2: Identify the oxidation states of the products in the options. 1. **C2H4 (Ethylene)**: - The oxidation state of carbon in C2H4 is calculated as follows: \[ 2x - 4 = 0 \implies 2x = 4 \implies x = +2 \] 2. **CH4 (Methane)**: - The oxidation state of carbon in CH4 is: \[ x + 4(-1) = 0 \implies x - 4 = 0 \implies x = -4 \] 3. **C2H2 (Acetylene)**: - The oxidation state of carbon in C2H2 is: \[ 2x - 2 = 0 \implies 2x = 2 \implies x = +1 \] 4. **C (Carbon)**: - The oxidation state of carbon in elemental carbon is 0. ### Step 3: Compare the oxidation states. - The oxidation states we found are: - C2H4: +2 - CH4: -4 - C2H2: +1 - C: 0 ### Step 4: Identify the lowest oxidation state. - The lowest oxidation state among the products is -4, which corresponds to methane (CH4). ### Step 5: Conclusion. - Therefore, the best reductant that reduces chloroform to its lowest oxidation state is **CH4** (methane). ### Final Answer: The best reductant reduces chloroform to **CH4** (methane). ---
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