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A compound (A) is formed by the reaction...

A compound (A) is formed by the reaction of ethylene with bromine which on reacting with aqueous KOH gives a compound (B). The compound (B) can also be prepared by the reaction of ethylene with the following:

A

Baeyer’s reagent

B

Oxygen in the presence of silver catalyst and then acidic hydrolysis

C

performic acid and the product undergoes acidic hydrolysis

D

All of the above

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we will follow these steps: ### Step 1: Identify Compound A The question states that compound A is formed by the reaction of ethylene (C2H4) with bromine (Br2). This reaction is an addition reaction where bromine adds across the double bond of ethylene. **Chemical Reaction:** \[ C_2H_4 + Br_2 \rightarrow C_2H_4Br_2 \] **Compound A:** 1,2-dibromoethane (C2H4Br2) ### Step 2: Identify Compound B The question mentions that compound A (1,2-dibromoethane) reacts with aqueous KOH to form compound B. In this case, KOH acts as a nucleophile and replaces one of the bromine atoms with a hydroxyl group (OH), resulting in the formation of ethylene glycol. **Chemical Reaction:** \[ C_2H_4Br_2 + KOH \rightarrow C_2H_4(OH)_2 + KBr \] **Compound B:** Ethylene glycol (C2H6O2) ### Step 3: Alternative Preparations for Compound B The question asks how compound B (ethylene glycol) can also be prepared from ethylene. We can consider the following methods: 1. **Baeyer's Reagent (Acidified KMnO4):** - Ethylene reacts with Baeyer's reagent, which oxidizes the double bond and forms ethylene glycol. - **Chemical Reaction:** \[ C_2H_4 + [O] \rightarrow C_2H_6O_2 \] 2. **Reaction with Oxygen in the Presence of Silver Catalyst:** - Ethylene can react with oxygen in the presence of a silver catalyst to form an epoxide, which upon acid hydrolysis yields ethylene glycol. - **Chemical Reaction:** \[ C_2H_4 + O \xrightarrow{Ag} \text{Epoxide} \xrightarrow{H_2O/H^+} C_2H_6O_2 \] 3. **Reaction with Performic Acid followed by Acid Hydrolysis:** - Ethylene reacts with performic acid to form an epoxide, which upon acid hydrolysis also yields ethylene glycol. - **Chemical Reaction:** \[ C_2H_4 + \text{Performic Acid} \rightarrow \text{Epoxide} \xrightarrow{H_2O/H^+} C_2H_6O_2 \] ### Conclusion All three methods mentioned above can be used to prepare compound B (ethylene glycol) from ethylene. Therefore, the answer to the question is that compound B can be prepared by all of the above methods. ### Final Answer: All of the above methods can prepare compound B (ethylene glycol). ---
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