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Wurtz reaction of methyl iodide yields a...

Wurtz reaction of methyl iodide yields an organic compound X. Which one of the following reactions also yields X?

A

`C_(2)H_(5)`Cl + Mg `overset("dryether")(rarr)`

B

`C_(2)H_(5)` Cl + `"LiAlH"_(4) (rarr)`

C

`C_(2)H_(5)`Cl + `C_(2) H_(5)"Ona" rarr `

D

`CHCl_(3) underset(Delta)overset("Ag powder")(rarr) `

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the Wurtz reaction of methyl iodide and the identification of an alternative reaction that yields the same organic compound, we can follow these steps: ### Step-by-Step Solution: 1. **Understand the Wurtz Reaction**: - The Wurtz reaction involves the coupling of alkyl halides in the presence of sodium metal. For methyl iodide (CH₃I), the reaction can be represented as: \[ 2 \text{CH}_3\text{I} + 2 \text{Na} \rightarrow \text{C}_2\text{H}_6 + 2 \text{NaI} \] - This means that two moles of methyl iodide react to form ethane (C₂H₆). 2. **Identify the Product**: - From the Wurtz reaction, we conclude that the organic compound X produced is ethane (C₂H₆). 3. **Evaluate Alternative Reactions**: - We need to check which of the given reactions also produces ethane (C₂H₆). 4. **Analyze Each Given Reaction**: - **Reaction A**: C₂H₅Cl + Mg → C₂H₅MgCl (Grignard reagent) - This reaction does not produce ethane; it produces a Grignard reagent. - **Reaction B**: C₂H₅Cl + LiAlH₄ → C₂H₆ + Cl⁻ - In this reaction, lithium aluminium hydride (LiAlH₄) acts as a reducing agent. It replaces the chlorine atom in chloroethane (C₂H₅Cl) with a hydrogen atom, yielding ethane (C₂H₆). This is a valid reaction that produces ethane. - **Reaction C**: C₂H₅Cl + C₂H₅O⁻ → C₂H₅-O-C₂H₅ + Cl⁻ - This reaction leads to the formation of diethyl ether, not ethane. - **Reaction D**: 2 CHCl₃ + Ag → C₂H₂ + 6 AgCl - This reaction produces ethyne (C₂H₂), not ethane. 5. **Conclusion**: - The only reaction that also yields ethane (C₂H₆) is **Reaction B**: C₂H₅Cl + LiAlH₄ → C₂H₆ + Cl⁻. ### Final Answer: The reaction that also yields the organic compound X (ethane) is: **C₂H₅Cl + LiAlH₄ → C₂H₆ + Cl⁻ (Reaction B)**.
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