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R-CH=CH(2) reacts with B(2) H(6) in...

`R-CH=CH_(2)` reacts with `B_(2) H_(6) ` in presence of `H_(2) O_(2)` to give :

A

`RCOCH_(3)`

B

`RCHOH CH_(2) OH`

C

`RCH_(2) CH_(2)OH`

D

`RCH_(2) CHO`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the question regarding the reaction of the alkene \( R-CH=CH_2 \) with \( B_2H_6 \) in the presence of \( H_2O_2 \), we can follow these steps: ### Step 1: Identify the Reaction Type The reaction of an alkene with diborane (\( B_2H_6 \)) followed by hydrogen peroxide (\( H_2O_2 \)) is known as the Hydroboration-Oxidation reaction. This reaction is characterized by the addition of water across the double bond. **Hint:** Remember that Hydroboration-Oxidation involves the addition of boron and then oxidation to form an alcohol. ### Step 2: Hydroboration Step In the hydroboration step, diborane (\( B_2H_6 \)) adds across the double bond of the alkene. The boron atom attaches to the less substituted carbon (the terminal carbon in this case), while a hydrogen atom attaches to the more substituted carbon. This follows the anti-Markovnikov rule. For the alkene \( R-CH=CH_2 \): - The boron atom (\( B \)) will attach to the \( CH_2 \) end, and a hydrogen atom will attach to the \( CH \) end. The intermediate formed will be: \[ R-CH_2-CH_2-BH_2 \] **Hint:** Focus on the anti-Markovnikov addition where boron attaches to the less substituted carbon. ### Step 3: Oxidation Step In the oxidation step, the trialkyl borane formed in the previous step reacts with hydrogen peroxide (\( H_2O_2 \)) in the presence of a base (like \( NaOH \) or \( KOH \)). This leads to the replacement of the boron atom with a hydroxyl group (\( OH \)). The reaction can be summarized as: \[ R-CH_2-CH_2-BH_2 + H_2O_2 \rightarrow R-CH_2-CH_2-OH + B(OH)_2 \] **Hint:** Remember that the hydroxyl group will attach to the carbon that has more hydrogen atoms, following the anti-Markovnikov rule. ### Step 4: Final Product The final product of this reaction will be a primary alcohol: \[ R-CH_2-CH_2-OH \] This indicates that the \( OH \) group is attached to the carbon that was originally part of the double bond and had more hydrogen atoms. **Hint:** The product is a primary alcohol due to the addition of the hydroxyl group to the less substituted carbon. ### Conclusion Thus, the product formed when \( R-CH=CH_2 \) reacts with \( B_2H_6 \) in the presence of \( H_2O_2 \) is: \[ R-CH_2-CH_2-OH \] (a primary alcohol).
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