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The compound obtained by the hydrolysis ...

The compound obtained by the hydrolysis of the adduct formed by the reaction of ethyl magnesium bromide and acetadehyde is :

A

Propanol

B

2-methyl-1-Propanol

C

2-Butanol

D

2-methyl-2-butanol

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to determine the compound obtained by the hydrolysis of the adduct formed by the reaction of ethyl magnesium bromide (C2H5MgBr) and acetaldehyde (CH3CHO). Here's a step-by-step breakdown of the process: ### Step 1: Identify the Reactants The reactants involved are: - Ethyl magnesium bromide (C2H5MgBr), which is a Grignard reagent. - Acetaldehyde (CH3CHO). ### Step 2: Understand the Reaction Mechanism In this reaction, the Grignard reagent acts as a nucleophile. The ethyl group (C2H5) from the Grignard reagent will attack the carbonyl carbon of acetaldehyde. ### Step 3: Form the Adduct When the nucleophile attacks, it forms an alkoxide intermediate. The reaction can be represented as follows: - C2H5MgBr + CH3CHO → C2H5-CH(OH)-CH3 + MgBr(OH) Here, the ethyl group attaches to the carbonyl carbon of acetaldehyde, resulting in the formation of a tetrahedral alkoxide intermediate. ### Step 4: Hydrolysis of the Adduct The next step involves hydrolysis of the alkoxide intermediate. When we add water (H2O) or an acid (H3O+), the alkoxide will be converted into an alcohol: - C2H5-CH(OH)-CH3 + H2O → C2H5-CH(OH)-CH3 (butanol) ### Step 5: Identify the Final Product The resulting compound after hydrolysis is 2-butanol (butan-2-ol). This compound has four carbon atoms with a hydroxyl group (-OH) on the second carbon. ### Conclusion The compound obtained by the hydrolysis of the adduct formed by the reaction of ethyl magnesium bromide and acetaldehyde is **2-butanol**. ---
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