Home
Class 12
CHEMISTRY
The compound A , B and C in the reaction...

The compound A , B and C in the reaction sequence
`CH_(3) - CH_(2) OH overset(PBr_(3))to A overset(Alc. KOH) to B overset(Br_(2))to C` are given by the set :

A

Ethyl bromide, `CH_(3) CH_(2) OH , CH_(3) CHBr_(2)`

B

`C_(2)H_(5) Br, CH -= CH , CH_(2) = CHBr`

C

`C_(2) H_(5) Br, CH_(2) = CH_(2) , CH_(2)Br- CH_(2)Br`

D

`C_(2) H_(5)Br, CH_(3)CH_(2)OH, BrCH_(2)- CH_(2)Br`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we will identify the compounds A, B, and C in the given reaction sequence step by step. ### Step 1: Identify Compound A The starting compound is ethyl alcohol, which is represented as \( CH_3CH_2OH \). When ethyl alcohol reacts with phosphorus tribromide (\( PBr_3 \)), the hydroxyl group (\( -OH \)) is replaced by a bromine atom (\( -Br \)). This reaction converts the alcohol into an alkyl bromide. **Reaction:** \[ CH_3CH_2OH + PBr_3 \rightarrow CH_3CH_2Br + HBr + H_3PO_3 \] Thus, compound A is: \[ A = CH_3CH_2Br \] (ethyl bromide) ### Step 2: Identify Compound B Next, we react compound A (ethyl bromide) with alcoholic potassium hydroxide (\( Alc. KOH \)). In this reaction, an elimination reaction occurs where a bromine atom is removed along with a hydrogen atom from the adjacent carbon, resulting in the formation of a double bond. **Reaction:** \[ CH_3CH_2Br + Alc. KOH \rightarrow CH_2=CH_2 + KBr + H_2O \] Thus, compound B is: \[ B = CH_2=CH_2 \] (ethylene or ethene) ### Step 3: Identify Compound C Finally, compound B (ethylene) reacts with bromine (\( Br_2 \)). In this reaction, the double bond in ethylene is broken, and two bromine atoms add across the double bond, resulting in the formation of 1,2-dibromoethane. **Reaction:** \[ CH_2=CH_2 + Br_2 \rightarrow CH_2Br-CH_2Br \] Thus, compound C is: \[ C = CH_2Br-CH_2Br \] (1,2-dibromoethane) ### Summary of Compounds - Compound A: \( CH_3CH_2Br \) (ethyl bromide) - Compound B: \( CH_2=CH_2 \) (ethylene) - Compound C: \( CH_2Br-CH_2Br \) (1,2-dibromoethane)
Promotional Banner

Similar Questions

Explore conceptually related problems

In the reaction sequence CH_(3)-CH_(2)-COOH overset(Br_(2)//PBr_(3))tox overset(Br_(2))toy overset(H_(2)O)to

In the following reaction order , B is CH_(3)CH_(2)COOH overset (P//Br_(2)) to A overset (alc KOH) underset (H^(+)) to B

In the reaction CH_(COOH overset (LiAIH) to A overset (PCI_(5)) to B overset (alc KOH) to C

Ph-CH_(2)-CH=CH-CH_(3) overset((i)Br_(2))underset((ii)Alc.KOH)to

Identify A,B and C in the following reaction sequence compounds : . CH_(3) CH_(2) OH overset(SoCl_(2)) to A underset("dryacetone")overset(+KI) to B overset(AqCN)to C

Write the structures of the products A and B of the following reactions : BrH_(2)C - CH_(2) Br overset(Alc. KOH) to A overset(NaNH_(2))to B

Complete the following reactions: CH_(3)CH_(2)CH_(2)OH overset(SOCl_(2)) to? overset(alc. KOH) to? overset(HBr) to ? overset(aq. KOH) to

Write the structures of compounds A, B and Cin the following reactions: (a) CH_(3) - COOH overset(NH_(3) // Delta)(to) A overset(Br_(2) // KOH(aq))(to) B overset(CHCl_(3) + alc. KOH)(to) C (b) C_(6)H_(5)N_(2)^(+)BF_(4)^(-) underset(Delta)overset(NaNO_(2) // Cu)(to) A overset(Fe // HCl)(to) B overset(CH_(3)COCl // "pyridine")(to) C

In the reaction CH_(3)CO OH overset(LiAlH_(4))toA overset(PCl_(5))toB overset(Alc. KOH)toC The product C is