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Heating mxiture of ethyl alcohol and ace...

Heating mxiture of ethyl alcohol and acetic acid in presence of conc. ` H_(2) SO_(4)` produces a fruity smelling compound. This reaction is called :

A

Neutralisation

B

Ester hydrolysis

C

Esterification

D

Williamson's synthesis

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The correct Answer is:
To solve the question regarding the reaction between ethyl alcohol and acetic acid in the presence of concentrated sulfuric acid, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Reactants**: - Ethyl alcohol (ethanol) has the formula CH₃CH₂OH. - Acetic acid has the formula CH₃COOH. 2. **Understand the Role of Concentrated Sulfuric Acid**: - Concentrated sulfuric acid (H₂SO₄) acts as a catalyst in this reaction. It helps in the dehydration process and increases the electrophilicity of the acetic acid, making it more reactive. 3. **Formation of Carbocation**: - When acetic acid is protonated by sulfuric acid, it forms a carbocation. The oxygen in acetic acid donates a lone pair to the proton (H⁺), resulting in a positively charged intermediate. 4. **Nucleophilic Attack**: - Ethyl alcohol (ethanol) acts as a nucleophile. The lone pair of electrons on the oxygen atom of ethanol attacks the carbocation formed from acetic acid. 5. **Formation of Ester**: - After the nucleophilic attack, a tetrahedral intermediate is formed. This intermediate then loses a water molecule (dehydration), resulting in the formation of an ester. - The product formed is ethyl acetate (CH₃COOCH₂CH₃), which is known for its fruity smell. 6. **Conclusion**: - The reaction described is called **Esterification**, which is the process of forming an ester from an alcohol and an acid. ### Final Answer: The reaction of heating a mixture of ethyl alcohol and acetic acid in the presence of concentrated sulfuric acid produces a fruity smelling compound, and this reaction is called **Esterification**. ---
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