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A compound of carbon, hydrogen, and nitr...

A compound of carbon, hydrogen, and nitrogen contains the three elements in the respective ratio of `9 : 1 : 3.5` Calculculate the empirical formula. If the molecular weight of the compound is 108, what its molecular formula?

Text Solution

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As the provided ratio is by mass so let us convert the masses into atoms and establish the ratio by atoms as `(9)/(12):(1)/(1):(7)/(2xx14)=(3)/(4):(1)/(1):(1)/(4)=3:4:1`. So the empirical formula of the compound will be `C_(3)H_(4)N_(1)` which has an empirical mass value of 54g/mole. As the molecular mass is given to be 108g/mole so, the value of `n=("Molecular Mass")/("Empirical Mass")=(108)/(54)=2.`
So, molecular formula = Empirical formula `xxn` that is `(C_(3)H_(4)N_(1))_(2)=C_(6)H_(8)N_(2).`
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