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N(2) is less reactive than CN^(-) due to...

`N_(2)` is less reactive than `CN^(-)` due to

A

Presence of more electrons in orbitals

B

Absence of dipole moment

C

Difference in spin quantum no

D

A trpile bond between nitrogen atoms

Text Solution

AI Generated Solution

The correct Answer is:
To determine why \( N_2 \) is less reactive than \( CN^- \), we can analyze the molecular structure and properties of both species step by step. ### Step 1: Analyze the molecular structure of \( N_2 \) - \( N_2 \) consists of two nitrogen atoms connected by a triple bond, represented as \( N \equiv N \). - This molecule is non-polar because the two nitrogen atoms have the same electronegativity, resulting in no charge separation. ### Step 2: Analyze the molecular structure of \( CN^- \) - \( CN^- \) (cyanide ion) also has a triple bond between carbon and nitrogen, represented as \( C \equiv N \). - However, the cyanide ion carries a negative charge, which introduces a dipole moment due to the difference in electronegativity between carbon and nitrogen. ### Step 3: Compare the dipole moments - The dipole moment of \( N_2 \) is zero because it is non-polar. - The dipole moment of \( CN^- \) is non-zero due to the presence of the negative charge, making it a polar molecule. ### Step 4: Relate polarity to reactivity - Reactivity in chemical species is often influenced by polarity. Polar molecules tend to be more reactive because they can interact with other charged or polar species. - Since \( N_2 \) is non-polar and has a dipole moment of zero, it is less reactive compared to the polar \( CN^- \). ### Step 5: Conclusion - The primary reason \( N_2 \) is less reactive than \( CN^- \) is the absence of a dipole moment in \( N_2 \). The lack of polarity means \( N_2 \) does not readily engage in chemical reactions, while the polar \( CN^- \) can react due to its charge. ### Final Answer \( N_2 \) is less reactive than \( CN^- \) due to the absence of a dipole moment in \( N_2 \). ---
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