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Any gas shows maximum deviation from ide...

Any gas shows maximum deviation from ideal gas behaviour at

A

` 0^(@)C` and 1 atmospheric pressure

B

`100^(@)C` and 2 atmospheric pressure

C

` –100^(@)C` and 5 atmospheric pressure

D

`500^(@)C` and 1 atmospheric pressure

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The correct Answer is:
To determine the conditions under which any gas shows maximum deviation from ideal gas behavior, we can follow these steps: ### Step 1: Understand Ideal Gas Behavior The ideal gas behavior is described by the equation: \[ PV = nRT \] where \( P \) is pressure, \( V \) is volume, \( n \) is the number of moles, \( R \) is the ideal gas constant, and \( T \) is the temperature. ### Step 2: Understand Real Gas Behavior Real gases deviate from ideal behavior, and this deviation can be expressed using the compressibility factor \( Z \): \[ Z = \frac{PV}{nRT} \] For an ideal gas, \( Z = 1 \). For real gases, \( Z \) can be greater or less than 1 depending on the conditions. ### Step 3: Identify the Factors Affecting Deviation The deviation from ideal behavior is influenced by: - **Pressure**: At high pressures, gas molecules are forced closer together, leading to interactions that deviate from ideal behavior. - **Temperature**: At low temperatures, gas molecules have lower kinetic energy, which can enhance intermolecular attractions and lead to deviations. ### Step 4: Analyze Conditions for Maximum Deviation From the Van der Waals equation, which accounts for intermolecular forces and the volume occupied by gas molecules, we can conclude: - At **high pressure**, the volume of the gas decreases significantly, leading to increased interactions between molecules. - At **low temperature**, the kinetic energy of the gas molecules decreases, allowing these interactions to have a more pronounced effect. ### Step 5: Conclusion Thus, the maximum deviation from ideal gas behavior occurs at: - **High pressure** - **Low temperature** ### Final Answer: Any gas shows maximum deviation from ideal gas behavior at **high pressure and low temperature**. ---
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