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1 mole of H(2)O is vaporised at 100^(@)C...

1 mole of `H_(2)O` is vaporised at `100^(@)C` and 1 atm pressure. If the latent heat of vaporisation of water is x J/g, then `Delta S` in terms of J/mole K is given by

A

`(x)/(373)`

B

`(18x)/(300)`

C

`(18x)/(373)`

D

`(1)/(2)xx(18x)/(373)`

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem, we need to calculate the change in entropy (ΔS) when 1 mole of water (H₂O) is vaporized at 100°C and 1 atm pressure. The latent heat of vaporization is given as x J/g. ### Step-by-Step Solution: 1. **Identify the Latent Heat of Vaporization**: - The latent heat of vaporization (L) for water is given as x J/g. - For 1 mole of water, which has a molar mass of 18 g, the total heat required (Q) for vaporization is: \[ Q = 18 \, \text{g} \times x \, \text{J/g} = 18x \, \text{J} \] 2. **Convert Temperature to Kelvin**: - The temperature at which the vaporization occurs is given as 100°C. To convert this to Kelvin: \[ T = 100 + 273 = 373 \, \text{K} \] 3. **Calculate the Change in Entropy (ΔS)**: - The change in entropy (ΔS) during a phase transition can be calculated using the formula: \[ \Delta S = \frac{Q}{T} \] - Substituting the values we found: \[ \Delta S = \frac{18x \, \text{J}}{373 \, \text{K}} = \frac{18x}{373} \, \text{J/mol K} \] 4. **Final Expression for ΔS**: - Therefore, the change in entropy (ΔS) for the vaporization of 1 mole of water is: \[ \Delta S = \frac{18x}{373} \, \text{J/mol K} \] ### Conclusion: The final answer for ΔS in terms of J/mol K is: \[ \Delta S = \frac{18x}{373} \, \text{J/mol K} \]
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