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The Delta S for the vaporisation of 1 mo...

The `Delta S` for the vaporisation of 1 mol of water is 88.3 J/mole K. The value of `Delta S` for the condensation of 1 mole of water vapour will be

A

88.3 J/mol K

B

`(88.3)^(2)` J/mol K

C

`-88.3` J/mol K

D

`(1)/(88.3)` J/mol K

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The correct Answer is:
To solve the problem, we need to understand the relationship between the entropy change (ΔS) for the vaporization and condensation processes of water. ### Step-by-Step Solution: 1. **Identify the Given Information:** - The ΔS for the vaporization of 1 mole of water is given as 88.3 J/mole K. 2. **Understand the Processes:** - Vaporization is the process where liquid water (H₂O in liquid state) converts to water vapor (H₂O in gaseous state). - Condensation is the reverse process, where water vapor (H₂O in gaseous state) converts back to liquid water (H₂O in liquid state). 3. **Recognize the Relationship Between ΔS for Vaporization and Condensation:** - ΔS is a state function, meaning it depends only on the initial and final states, not on the path taken. - When a process is reversed, the sign of ΔS changes. Therefore, the ΔS for condensation will be the negative of the ΔS for vaporization. 4. **Calculate ΔS for Condensation:** - Since the ΔS for vaporization is +88.3 J/mole K, the ΔS for condensation will be: \[ \Delta S_{\text{condensation}} = -\Delta S_{\text{vaporization}} = -88.3 \, \text{J/mole K} \] 5. **Final Answer:** - The value of ΔS for the condensation of 1 mole of water vapor is **-88.3 J/mole K**.
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