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An AB(2) type structure is found in:...

An `AB_(2)` type structure is found in:

A

NaCl

B

`AI_(2)O_(3)`

C

`CaF_(2)`

D

`N_(2)O`

Text Solution

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The correct Answer is:
To determine the compound that exhibits an AB₂ type structure, we can follow these steps: ### Step 1: Understand the AB₂ Structure The AB₂ structure indicates that for every one cation (A), there are two anions (B). In this structure, the cation is typically larger than the anion. **Hint:** Remember that in AB₂ structures, the ratio of cations to anions is crucial. ### Step 2: Identify Examples of AB₂ Structures Common examples of compounds with an AB₂ structure include calcium fluoride (CaF₂) and strontium fluoride (SrF₂). In these compounds, the cation (Ca²⁺ or Sr²⁺) is larger than the anion (F⁻). **Hint:** Look for compounds where the cation is a divalent metal and the anion is a monovalent non-metal. ### Step 3: Analyze the Ionic Radii In the AB₂ structure, the ionic radii ratio of the anion to the cation is significant. For CaF₂, the ionic radius of Ca²⁺ is larger than that of F⁻. The ratio of the radii (r⁻/r²⁺) falls between 0.225 and 0.414, which is characteristic of an AB₂ type structure. **Hint:** Check the ionic radii values in a table to confirm the size relationship between cations and anions. ### Step 4: Confirm the Structure In the case of CaF₂, the structure can be described as follows: - The Ca²⁺ ions form a face-centered cubic (FCC) lattice. - The F⁻ ions occupy the tetrahedral voids within the lattice. This arrangement confirms the AB₂ type structure. **Hint:** Visualizing the crystal structure can help in understanding how the ions are arranged. ### Step 5: Conclusion Based on the analysis, the compound that exhibits an AB₂ type structure is calcium fluoride (CaF₂). **Final Answer:** The AB₂ type structure is found in CaF₂ (Calcium Fluoride).
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