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In the reaction CH(3)COOHoverset(PCl(5...

In the reaction
`CH_(3)COOHoverset(PCl_(5))(to)(A)overset(NH_(3))(to)(B)overset(NaBrO)(to)(C)`
the final product (C) is:

A

Ammonium acetate

B

Acetamide

C

Amino methane

D

Ethanal

Text Solution

AI Generated Solution

The correct Answer is:
To solve the problem step by step, we will analyze the reactions involved and identify the final product (C) in the given sequence of reactions. ### Step 1: Reaction of Acetic Acid with PCl5 - **Starting Compound**: Acetic Acid (CH₃COOH) - **Reagent**: PCl₅ - **Reaction**: PCl₅ reacts with the hydroxyl (OH) group in acetic acid, replacing it with a chlorine (Cl) atom. **Product A**: The product formed is Acetyl Chloride (CH₃COCl). ### Step 2: Reaction of Acetyl Chloride with Ammonia - **Starting Compound**: Acetyl Chloride (CH₃COCl) - **Reagent**: Ammonia (NH₃) - **Reaction**: Ammonia acts as a nucleophile and attacks the electrophilic carbon of the carbonyl group in acetyl chloride. This leads to the formation of an intermediate that eventually loses HCl. **Product B**: The product formed is Acetamide (CH₃CONH₂). ### Step 3: Reaction of Acetamide with NaBrO - **Starting Compound**: Acetamide (CH₃CONH₂) - **Reagent**: Sodium Bromate (NaBrO) - **Reaction**: This reaction is a classic example of the Hofmann degradation reaction. The amide reacts with NaBrO, where the nitrogen's hydrogen is abstracted, leading to the formation of a bromamide intermediate. This intermediate undergoes rearrangement and elimination to form a primary amine. **Product C**: The final product formed is Methylamine (CH₃NH₂). ### Final Answer The final product (C) is **Methylamine (CH₃NH₂)**. ---
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