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Arrange the following alkyl halides in d...

Arrange the following alkyl halides in decreasing order of the rate or `beta`-elimination reaction alcoholic KOH.
A. `CH_(3)-underset(CH_(3))underset(|)overset(H)overset(|)(C)-CH_(2)Br`
B. `CH_(3)-CH_(2)-Br`
C. `CH_(3)-CH_(2)-CH_(2)-Br`

A

`A gt B gt C`

B

`C gt B gt A`

C

`B gt C gt A`

D

`A gt C gt B`

Text Solution

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The correct Answer is:
To arrange the given alkyl halides in decreasing order of the rate of β-elimination reaction with alcoholic KOH, we need to analyze the structure of each compound and the stability of the alkenes formed after the elimination reaction. ### Step-by-step Solution: 1. **Identify the Alkyl Halides**: - A: `CH3-CH(CH3)-CH2Br` (1-bromo-2-methylpropane) - B: `CH3-CH2Br` (ethyl bromide) - C: `CH3-CH2-CH2Br` (1-bromopropane) 2. **Understand β-Elimination**: - β-elimination involves the removal of a hydrogen atom from the β-carbon and the halogen (Br) from the α-carbon, resulting in the formation of an alkene. The stability of the alkene formed is crucial. 3. **Determine the Substitution of the Alkenes**: - For compound A (1-bromo-2-methylpropane): - The elimination will yield 2-methylpropene, which is a disubstituted alkene (two alkyl groups attached to the double bond). - For compound B (ethyl bromide): - The elimination will yield ethene, which is a non-substituted alkene (no alkyl groups attached to the double bond). - For compound C (1-bromopropane): - The elimination will yield propene, which is a monosubstituted alkene (one alkyl group attached to the double bond). 4. **Compare the Stability of the Alkenes**: - Disubstituted alkenes are more stable than monosubstituted alkenes, which are more stable than non-substituted alkenes. Thus, the order of stability is: - 2-methylpropene (disubstituted) > propene (monosubstituted) > ethene (non-substituted). 5. **Rate of β-Elimination Reaction**: - The rate of β-elimination reaction is directly related to the stability of the alkene formed. Therefore, the order of the rate of reaction will be: - A (1-bromo-2-methylpropane) > C (1-bromopropane) > B (ethyl bromide). 6. **Final Arrangement**: - The decreasing order of the rate of β-elimination reaction with alcoholic KOH is: - A > C > B. ### Conclusion: The correct order is: 1. A: `CH3-CH(CH3)-CH2Br` (1-bromo-2-methylpropane) 2. C: `CH3-CH2-CH2Br` (1-bromopropane) 3. B: `CH3-CH2Br` (ethyl bromide)

To arrange the given alkyl halides in decreasing order of the rate of β-elimination reaction with alcoholic KOH, we need to analyze the structure of each compound and the stability of the alkenes formed after the elimination reaction. ### Step-by-step Solution: 1. **Identify the Alkyl Halides**: - A: `CH3-CH(CH3)-CH2Br` (1-bromo-2-methylpropane) - B: `CH3-CH2Br` (ethyl bromide) - C: `CH3-CH2-CH2Br` (1-bromopropane) ...
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