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Assertion ( A) Phosphorus chlorides ( tr...

Assertion ( A) Phosphorus chlorides ( tri and penta) are preferred over thionyl chloride for the preparation of alkyl chlorides from alcohols.
Reason (R) Phosphorus chlorides give pure alkyl halides.

A

Assertion and reason both are correct and reason is correct explanation of assertion

B

Assertion and reason both are wrong statements

C

Assertion is correct but reason is wrong statement

D

Assertion is wrong but reason is correct statement.

Text Solution

Verified by Experts

The correct Answer is:
B

Asertion and reason both are wrong statements.
Correct Assertion Thionyl chloride le preferred over `PCl_(3)` and `PCI_(5)` for the preparation of alkyl chłorides from alcohols.
Correct Reason Thionyl chloride gives pure alkyl halide as other two products `(SO_(2)+ HCl)` are escapable gases.
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NCERT EXEMPLAR-HALOALKANES AND HALOARENES-Haloalkanes And Haloarenes
  1. Cyanide ion acts as an ambident nucleophille. From which end it acts a...

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  2. Match the compounds given in column I with the effects given in Column...

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  3. Match the items of Column I and Column II

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  4. Match the structures of compounds given in Column I with the classes o...

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  5. Match the reactions given in Column I with the types of reactions give...

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  6. Match the structures given in Column I with the names in Column II

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  7. Match the reactions given in Column I with the names givn in Column II...

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  8. Assertion ( A) Phosphorus chlorides ( tri and penta) are preferred ove...

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  9. Assertion( A) The boiling points of alkyl halides decrease in the orde...

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  10. Assertion( A) KCN reacts with methyl chloride to give methyl isocyanid...

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  11. Assertion (A) tert-butyl bromide undergoes Wurtz reaction to give 2,2,...

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  12. Assertion (A) Presence of a nitro group at ortho or para position incr...

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  13. Assertion: In monohaloarenes, further electrophilic substitution occur...

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  14. Assertion: Aryl iodides can be prepared by reaction of arenes with iod...

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  15. Assertion: It is difficult to replace chlorine by -OH in chlorobenzene...

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  16. Assertion (A) Hydrolysis of (-)-2-bromooctane proceeds with inversion ...

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  17. Assertion (A) Nitration of chlorobenzene leads to the formation of m-n...

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  18. Some alkyl halides undergo substitutionn whereas some undergo eliminat...

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  19. Some halogen containing compounds are useful in daily life. Some compo...

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  20. Aryl halides are less reactive towards nucleophilic substitution react...

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