Home
Class 12
CHEMISTRY
KMnO(4) acts as on oxidising agent in al...

`KMnO_(4)` acts as on oxidising agent in alkaline medium. When alkaline `KMnO_(4)` is treated with `KI`, iodide ion is oxidised to `…………….`

A

`I_(2)`

B

`IO^(-)`

C

`IO_(3)^(-)`

D

`IO_(4)^(-)`

Text Solution

Verified by Experts

The correct Answer is:
C

`KMnO_(4)` acts as an oxidising agent in alkaline medium. When alkaline `KMnO_(4)` is treated with `KI`, iodide ion is oxidised to `IO_(3)^(-)`.
Reaction `2KMnO_(4) + H_(2)O + KI rarr 2MnO_(4) + 2KOH + KIO_(3)`
or, `" "I^(-) + 6OH^(-) rarr IO_(3)^(-) + 3H_(2)O + 6e^(-)`
Promotional Banner

Topper's Solved these Questions

  • COORDINATION COMPOUNDS

    NCERT EXEMPLAR|Exercise Coordination Compounds|50 Videos
  • ELECTROCHEMISTRY

    NCERT EXEMPLAR|Exercise Electrochemistry|68 Videos

Similar Questions

Explore conceptually related problems

KMnO_(4) acts as an oxidising agent in acidic medium. The number of moles of KMnO_(4) that will be needed to react with one mole of sulphide ions in acidic solution is

NCERT EXEMPLAR-D AND F-BLOCK ELEMENTS-D And F-Block Elements
  1. Interstitial compounds are formed when small atoms are trapped inside ...

    Text Solution

    |

  2. The magnetic moment is associated with its spin angular momentum and o...

    Text Solution

    |

  3. KMnO(4) acts as on oxidising agent in alkaline medium. When alkaline K...

    Text Solution

    |

  4. Which of the following statements is not correct?

    Text Solution

    |

  5. When acidified K(2)Cr(2)O(7) solution is added to Sn^(2+) salts then S...

    Text Solution

    |

  6. Higher oxidation state of manganese in fluoride is +4 (MnF(4)) but hig...

    Text Solution

    |

  7. Although zirconium belongs to 4d transition series and hafnium to 5d t...

    Text Solution

    |

  8. Why HCl not used to make the mdeium acidic in oxidation reactions of K...

    Text Solution

    |

  9. Generally transition elements and their salts are coloured due to the ...

    Text Solution

    |

  10. Transition elements show magnetic moment due to spin and orbital motio...

    Text Solution

    |

  11. In the form of dichromate, Cr(VI) is a strong oxidising agent in acidi...

    Text Solution

    |

  12. Which of the following actinoids show oxidation states upto +7?

    Text Solution

    |

  13. General electronic configuration of actinoids is (n-2)f^(1-14)(n-1)d^(...

    Text Solution

    |

  14. Which of the following lanthanoids show +2 oxidation state besides the...

    Text Solution

    |

  15. Which of the following ions show higher spin only magnetic moment va...

    Text Solution

    |

  16. Transition elements form binary compounds with halogens. Which of the ...

    Text Solution

    |

  17. Which of the following will not act as oxidising agents?

    Text Solution

    |

  18. Although +3 is the characteristic oxidation state for lanthanoids but ...

    Text Solution

    |

  19. Why does copper not replace hydrogen from acids?

    Text Solution

    |

  20. Why E^(-) values for Mn, Ni and Zn are more negative than expected?

    Text Solution

    |