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Although fluorine is more electronegativ...

Although fluorine is more electronegative than oxygen, but the ability of oxygen to stabilise higher oxidation states exceeds that of fluorine. Why?

Text Solution

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Oxygen can form multiple bonds with metals, while fluorine can't form multiple bond with metals. Hence, oxygen has more ability to stabilize higher oxidation state rather than fluorine.
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Although flurorine is more electronegative than oxygen, but the ability of oxygen to stabilize higher oxidation states exceeds that of fluorine . Why ?

How would you account for the following: Both O_2 and F_2 stabilise high oxidation states but the ability of oxygen to stabilise the higher oxidation state exceeds that of fluorine.

Knowledge Check

  • Oxygen stablises higher oxidation state because

    A
    It is electronegative
    B
    Of its tendency to form double bond
    C
    Of small size
    D
    Of large size
  • Fluorine is more electronegative than nitrogen the best explanation is that

    A
    the avlence electron in F are on an average a little closer to the nucleus than in N
    B
    the charge of a F nucleus is +9 while that on N nucleus is +7
    C
    The valence electrons in F and N are in different shells and thus their energy are greatly different
    D
    electronegativity increase from left to right in each of the period
  • Fluorine is more electronegativity than nitrogen. The best explanation is that:

    A
    the valency electrons in F are on the average, a little farther to the nucleus than in N
    B
    the charge on a F nucleus is `+9`, while that on N nucleus is `+7`
    C
    the nitrogen has half filled valence shell electron configuration, `ns^(2)np^(3)` where as fluorine has partially filled electron configuration `ns^(2)np^(5)`
    D
    the electronegativity decreases from top to bottom in each of the group as the effect nuclear charge remains constant.
  • Similar Questions

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    Both O_(2) and F_(2) stabilize high oxidation states but the ability of oxygen to stabilize the higher oxidation state exceeds than that of flrorine. Account for this observation.

    Why does oxygen cannot exhibit higher oxidation state?

    Fluorine is more electronegative than chlorine. Is the statement true ?

    Fluorine is more reactive than chlorine because

    Oxygen cannot exhibit higher oxidation states due to