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Explain which is a stronger acid. CH(...

Explain which is a stronger acid.
`CH_(3) - CHO " "CH_(3) - NO_(2)`

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To determine which compound is a stronger acid between CH₃CHO (acetaldehyde) and CH₃NO₂ (nitromethane), we can analyze the effects of their functional groups on acidity. ### Step-by-Step Solution: 1. **Identify the Compounds**: - The first compound is CH₃CHO (acetaldehyde), which contains an aldehyde functional group (-CHO). - The second compound is CH₃NO₂ (nitromethane), which contains a nitro functional group (-NO₂). 2. **Understand Acidity**: - Acidity is related to the ability of a compound to donate a proton (H⁺). The more stable the conjugate base formed after deprotonation, the stronger the acid. 3. **Analyze the Functional Groups**: - The aldehyde group (-CHO) is a weak electron-withdrawing group due to its carbonyl (C=O) structure. - The nitro group (-NO₂) is a strong electron-withdrawing group due to its resonance and inductive effects. 4. **Stability of Conjugate Bases**: - When CH₃CHO donates a proton, it forms CH₃C(O⁻)H, where the negative charge is partially stabilized by the carbonyl group. - When CH₃NO₂ donates a proton, it forms CH₃NO₂⁻, where the negative charge is highly stabilized by the strong electron-withdrawing nitro group. 5. **Comparison of Stability**: - The conjugate base of CH₃NO₂ (nitromethane) is more stable than that of CH₃CHO (acetaldehyde) because the nitro group can delocalize the negative charge effectively through resonance and inductive effects. 6. **Conclusion**: - Since the conjugate base of CH₃NO₂ is more stable than that of CH₃CHO, CH₃NO₂ is the stronger acid. ### Final Answer: **CH₃NO₂ (nitromethane) is a stronger acid than CH₃CHO (acetaldehyde).**
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MOTION-GOC-Exercise - 3
  1. Explain which is a stronger acid CH(3)CH(3)&BrCH(2)NO(2)

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  2. Explain which is a stronger acid. CH(3)- overset(O)overset(||)C - C...

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  3. Explain which is a stronger acid. CH(3) - CHO " "CH(3) - NO(2)

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  4. Which of the following would you predict to be the stronger acid? (a...

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  5. Which of the following would you predict to be the stronger acid ? <b>...

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  6. Write increasing order of basic strength of following: (a) F^(Theta...

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  7. Write increasing order of basic strength of following: (a)CH(3)^(Th...

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  8. Write increasing order of basic strength of following: (a)CH(3)^(Th...

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  9. Correct order of basic strength in gas phase is (I) CH(3)-NH(2) (II...

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  10. Write increasing order of basic strength of following: (a)NH(3)" "...

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  11. Write increasing order of basic strength of following: (a)CH(3) - C...

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  12. Write increasing order of basic strength of following: (a)CH(3) -un...

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  13. Arrange the following compound in decreasing order of their basicity. ...

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  14. Arrange the following compound in decreasing order of their basicity. ...

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  15. Consider the following bases: (I) o-nitroaniline (II) m-nitroanili...

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  16. Consider the basicity of the following aromatic amines: (I) aniline ...

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  17. Which one of the following is least basic in character?

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  18. In each of the following pair of compounds, which is more basic in aqu...

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  19. In each of the following pair of compounds, which is more basic in aqu...

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  20. In each of the following pair of compounds, which is more basic in aqu...

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