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100ml of 0.3 N HCl is mixed with 200ml o...

100ml of 0.3 N HCl is mixed with 200ml of 0.6 N `H_(2)SO_(4)`. The final normality of the resulting solution will be -

A

0.1N

B

0.2N

C

0.3N

D

0.5N

Text Solution

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The correct Answer is:
To find the final normality of the resulting solution when mixing 100 ml of 0.3 N HCl with 200 ml of 0.6 N H₂SO₄, we can follow these steps: ### Step 1: Calculate the milliequivalents of HCl The formula to calculate milliequivalents (mEq) is: \[ \text{mEq} = \text{Normality (N)} \times \text{Volume (ml)} \] For HCl: - Normality (N) = 0.3 N - Volume = 100 ml Calculating: \[ \text{mEq of HCl} = 0.3 \, \text{N} \times 100 \, \text{ml} = 30 \, \text{mEq} \] ### Step 2: Calculate the milliequivalents of H₂SO₄ Using the same formula for H₂SO₄: - Normality (N) = 0.6 N - Volume = 200 ml Calculating: \[ \text{mEq of H₂SO₄} = 0.6 \, \text{N} \times 200 \, \text{ml} = 120 \, \text{mEq} \] ### Step 3: Calculate the total milliequivalents Now, we add the milliequivalents from both solutions: \[ \text{Total mEq} = \text{mEq of HCl} + \text{mEq of H₂SO₄} \] \[ \text{Total mEq} = 30 \, \text{mEq} + 120 \, \text{mEq} = 150 \, \text{mEq} \] ### Step 4: Calculate the total volume of the solution Now, we find the total volume of the mixed solution: \[ \text{Total Volume} = 100 \, \text{ml} + 200 \, \text{ml} = 300 \, \text{ml} \] ### Step 5: Calculate the final normality Finally, we can calculate the final normality (N) of the resulting solution using the formula: \[ \text{Final Normality} = \frac{\text{Total mEq}}{\text{Total Volume (ml)}} \] \[ \text{Final Normality} = \frac{150 \, \text{mEq}}{300 \, \text{ml}} = 0.5 \, \text{N} \] Thus, the final normality of the resulting solution is **0.5 N**. ---
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Knowledge Check

  • 100 mL of 0.3 N HCl were mixed with 200 mL of 0.6 N H_(2)SO_(4) solution. The final normality of acid was :

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    D
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