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The shape of XeF4 molecule according to ...

The shape of XeF4 molecule according to VSEPR theory is

A

Square planar

B

Square pyramid

C

Tetrahedral

D

Pyramidal

Text Solution

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The correct Answer is:
To determine the shape of the XeF4 molecule according to VSEPR theory, we can follow these steps: ### Step-by-Step Solution: 1. **Identify the Central Atom**: - The central atom in the XeF4 molecule is xenon (Xe). 2. **Count Valence Electrons**: - Xenon has 8 valence electrons (it is in group 18 of the periodic table). - Each fluorine (F) atom contributes 1 valence electron. Since there are 4 fluorine atoms, they contribute a total of 4 electrons. - Total valence electrons = 8 (from Xe) + 4 (from 4 F) = 12 valence electrons. 3. **Determine Bonding and Lone Pairs**: - In XeF4, xenon forms 4 single bonds with the 4 fluorine atoms. This uses up 4 pairs of electrons (8 electrons). - After forming these bonds, there are 4 valence electrons left, which will form 2 lone pairs on the xenon atom. 4. **Determine the Steric Number**: - The steric number is calculated as the number of bond pairs plus the number of lone pairs. - Steric number = 4 (bond pairs) + 2 (lone pairs) = 6. 5. **Predict the Geometry Using VSEPR Theory**: - According to VSEPR theory, a steric number of 6 corresponds to an octahedral arrangement of electron pairs. - However, since there are 2 lone pairs, they will occupy positions opposite each other to minimize repulsion, resulting in a square planar shape for the molecule. 6. **Conclusion**: - Therefore, the shape of the XeF4 molecule is square planar. ### Final Answer: The shape of the XeF4 molecule according to VSEPR theory is **square planar**. ---
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