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Account for the following: t-butyl chl...

Account for the following:
t-butyl chloride on heating with sodium methoxide gives 2-methylpropene instead of t-butylmethylether

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To account for why t-butyl chloride on heating with sodium methoxide gives 2-methylpropene instead of t-butyl methyl ether, we can break down the reaction mechanism step by step. ### Step 1: Understand the Reactants - **Tert-butyl chloride (t-butyl chloride)** is a tertiary alkyl halide with the formula (CH₃)₃CCl. - **Sodium methoxide (NaOCH₃)** is a strong nucleophile and base. ### Step 2: Analyze the Reaction Conditions - When t-butyl chloride is heated with sodium methoxide, the reaction conditions favor elimination rather than substitution. Heating typically promotes elimination reactions. ...
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(a) Account for the following : (i) o-nitrophenol is more steam volatile than p-nitrophenol. (ii) t-butyl chloride on heating with sodium methoxide gives 2-methylpropene instead of t-butymethylether. (b) Write the reaction involved in the following: i) Reimer-Tiemann reaction (ii) Friedal-Crafts Alkylation of Phenol (c) Give simple chemical test to distinguish between Ethanol and Phenol.

Tert-butyl chloride to 2-methylpropene

Knowledge Check

  • The reaction of t - butyl chloride and sodium ethoxide gives mainly

    A
    t - butyl ethyl ether
    B
    2,2 - dimethylbutane
    C
    2 - methylprop -1 - ene
    D
    isopropyl n- propyl ether
  • Sodium t-butoxide on treatment with ethyl bromide gives :

    A
    `CH_3-overset(CH_3)overset(|)underset(CH_3)underset(|)C-OCH_2CH_3`
    B
    `CH_3-overset(CH_3)overset(|)C=CH_2+CH_2=CH_2`
    C
    `CH_3-overset(CH_3)overset(|)underset(CH_3)underset(|)C-Br+CH_3CH_2ONa`
    D
    `CH_3-underset(CH_3)underset(|)C-CH=CH_2`
  • Reaction of t-butyl bromide with sodium methoxide produces

    A
    sodium tertiary butoxide
    B
    tertiary butyl methyl ether
    C
    isobutane
    D
    isobutylene
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