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Account for the following : (b) The Is...

Account for the following :
(b) The Ist ionization energy of the 5d series are higher than 3d and 4d, transition elements in respective groups.

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To account for the observation that the first ionization energy of the 5d series is higher than that of the 3d and 4d transition elements in their respective groups, we can break down the explanation into several key points: ### Step-by-Step Explanation: 1. **Understanding Ionization Energy**: - Ionization energy is the energy required to remove an electron from an atom in the gaseous state. Higher ionization energy indicates that it is more difficult to remove an electron. **Hint**: Remember that ionization energy increases across a period and decreases down a group in the periodic table. ...
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Explore conceptually related problems

How will you account for the following : (i) All scandium salt are white. (ii) The first ionisation enthalpy of the 5d transition elements are higher than those of 3d and 4d transition elements in respective group.

Why is first ionization energy of 5d elements higher than those of 3d and 4d elements ?

Knowledge Check

  • First IE of 5d seties element are higher than those of 3d and 4d series elements. This is due to:

    A
    bigger size of atoms of `5d` -series elements than `3d` series elements
    B
    Greater effective nuclear charge is experienced by valence electrons because of the weak shielding of the nuclear by `4f`-electrons in `5d` series.
    C
    (A) and (B) both
    D
    None of these

  • Among 3d transition series the IE

    A
    Increases regularly in moving from left to right
    B
    Decrease regularly in moving from left to right
    C
    Remains constant within the period
    D
    increases gradually within the period but the relativ increase is not sharp.

    • Similar Questions

    Explore conceptually related problems

    How do you account for the following: (i) all scandium salts are white ? (ii) the first ionisation enthalpies of 5d transition elements are higher than those of the 3d and 4d transition elements in respective groups ?

    Why are the ionization energies of 5 d elements than 3d elements ?

    Why are the ionisation energies of 5d elements greater than 3d elements?

    How would you account for the following ? (i) The atomic radii of the metals of the third (5d) series of transition elements are virtually the same as those of the corresponding members of the second (4d) series. (ii) The E^(@) value for the Mn^(3+)//Mn^(2+) couple is much more positive than that for Cr^(3+)//Cr^(2+) couple or Fe^(3+)//Fe^(2+) couple. (iii) The highest oxidation state of a metal is exhibited in its oxide or fluoride.

    How would you account for the following? (i) The atomic radii of the metals of the third (5d) series of transition elements are virtually the same as those of the corresponding member of the second (4d) serie (ii) Because oxygen and fluorine are highly electronegative elements and small in size.

    How would you account for the following? (i) The atomic radii of the metals of the third (5d) series of transition elements are virtually the same as those of the corresponding member of the second (4d) serie (ii) The E^(@) value for the Mn^(3+)//Mn^(2+) couple is much more positive than that for Cr^(3+)//Cr^(2+) couple of Fe^(3+)//Fe^(2+) couple. (iii) The highest oxidation state of a metal is exhibited in its oxides or fluoride.

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