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Which of the following statement is corr...

Which of the following statement is correct ?

A

Gluonic acid is a dicarboxylic acid

B

Gluconic acid is a partial oxidation product of glucose

C

Gluconic acid can form cyclic (aceta/hemiacetal) structure

D

Gluconic acid is obtained by oxidation of glucose with `HNO_3`

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AI Generated Solution

The correct Answer is:
To determine which statement about gluconic acid is correct, we will evaluate each option step by step. ### Step 1: Analyze Option A **Statement**: Gluconic acid is a dicarboxylic acid. **Evaluation**: - A dicarboxylic acid contains two carboxyl groups (–COOH). - Gluconic acid has only one carboxyl group in its structure. - Therefore, gluconic acid is classified as a monocarboxylic acid. **Conclusion**: This statement is **incorrect**. ### Step 2: Analyze Option B **Statement**: Gluconic acid is a partial oxidation product of glucose. **Evaluation**: - Glucose can undergo partial oxidation to form gluconic acid. - This can be achieved using a mild oxidizing agent such as bromine water. - Hence, gluconic acid is indeed derived from glucose through partial oxidation. **Conclusion**: This statement is **correct**. ### Step 3: Analyze Option C **Statement**: Gluconic acid can form cyclic structures like acetals or hemiacetals. **Evaluation**: - Cyclic structures can form from sugars, but gluconic acid has a carboxyl group that affects its ability to form such structures. - The presence of the carboxyl group makes the carbon less electrophilic, which inhibits the formation of cyclic structures. - Therefore, gluconic acid does not typically form cyclic structures. **Conclusion**: This statement is **incorrect**. ### Step 4: Analyze Option D **Statement**: Gluconic acid is obtained by oxidation of glucose with nitric acid. **Evaluation**: - Using nitric acid for oxidation leads to complete oxidation of glucose, resulting in the formation of saccharic acid, not gluconic acid. - Therefore, this statement is also incorrect. **Conclusion**: This statement is **incorrect**. ### Final Conclusion The only correct statement among the options provided is **Option B**: Gluconic acid is a partial oxidation product of glucose. ---
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