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Which of the following acts as an oxidis...

Which of the following acts as an oxidising as well as reducing agent ?

A

`Na_(2)O`

B

`H_2SO_4`

C

`HNO_3`

D

`HNO_2`

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The correct Answer is:
To determine which of the following acts as both an oxidizing agent and a reducing agent, we need to analyze the oxidation states of the elements involved. Here’s a step-by-step breakdown of the solution: ### Step 1: Understand the Definitions - **Oxidizing Agent**: A substance that can gain electrons (be reduced) and, in the process, oxidizes another substance. - **Reducing Agent**: A substance that can lose electrons (be oxidized) and, in the process, reduces another substance. ### Step 2: Identify the Elements We will consider common elements and compounds that are known to have variable oxidation states, particularly from the p-block of the periodic table. ### Step 3: Analyze Oxidation States 1. **Nitrogen (N)**: - Nitrogen has 5 valence electrons. - Its oxidation state can vary from -3 (in NH3) to +5 (in HNO3). - Therefore, nitrogen can act as a reducing agent when it goes from +3 to +5 (losing electrons) and as an oxidizing agent when it goes from +3 to -3 (gaining electrons). 2. **Sulfur (S)**: - Sulfur has 6 valence electrons. - Its oxidation state can vary from -2 (in H2S) to +6 (in H2SO4). - However, sulfur cannot act as both an oxidizing and reducing agent in the same way as nitrogen because it cannot easily transition from +6 to a lower oxidation state while also being able to oxidize other substances. 3. **HNO3 (Nitric Acid)**: - In HNO3, nitrogen is in the +5 oxidation state. - It cannot be reduced further to act as a reducing agent, hence it cannot serve both roles. ### Step 4: Conclusion From the analysis above, **Nitrogen** is the element that can act as both an oxidizing agent and a reducing agent due to its ability to exist in multiple oxidation states. ### Final Answer: **Nitrogen (N)** acts as both an oxidizing agent and a reducing agent. ---
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