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If Deltar(1) represents the difference i...

If `Deltar_(1)` represents the difference in radii of statonary orbitals for n = 3 and n = 4 in a hydrogen atom and `Deltar_(2)` represents the difference in radii of stationary orbits for n = 8 and n = 9, then the value of `(Deltar_(1))/(Deltar_(2))` is

A

0.71

B

0.41

C

2.43

D

14.82

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The correct Answer is:
To solve the problem, we need to calculate the differences in the radii of stationary orbits for the specified quantum numbers (n = 3 & n = 4 for Δr₁ and n = 8 & n = 9 for Δr₂) using the formula for the radius of the nth orbit in a hydrogen atom. ### Step-by-Step Solution: 1. **Identify the formula for the radius of stationary orbits:** The radius of the nth orbit in a hydrogen atom is given by: \[ r_n = 0.529 \frac{n^2}{Z} \text{ Angstroms} \] For hydrogen, \( Z = 1 \). 2. **Calculate Δr₁ (difference between n = 4 and n = 3):** \[ \Delta r_1 = r_4 - r_3 \] - Calculate \( r_4 \): \[ r_4 = 0.529 \times 4^2 = 0.529 \times 16 = 8.464 \text{ Angstroms} \] - Calculate \( r_3 \): \[ r_3 = 0.529 \times 3^2 = 0.529 \times 9 = 4.761 \text{ Angstroms} \] - Now, find Δr₁: \[ \Delta r_1 = 8.464 - 4.761 = 3.703 \text{ Angstroms} \] 3. **Calculate Δr₂ (difference between n = 9 and n = 8):** \[ \Delta r_2 = r_9 - r_8 \] - Calculate \( r_9 \): \[ r_9 = 0.529 \times 9^2 = 0.529 \times 81 = 42.849 \text{ Angstroms} \] - Calculate \( r_8 \): \[ r_8 = 0.529 \times 8^2 = 0.529 \times 64 = 33.856 \text{ Angstroms} \] - Now, find Δr₂: \[ \Delta r_2 = 42.849 - 33.856 = 8.993 \text{ Angstroms} \] 4. **Calculate the ratio \( \frac{\Delta r_1}{\Delta r_2} \):** \[ \frac{\Delta r_1}{\Delta r_2} = \frac{3.703}{8.993} \] - Performing the division: \[ \frac{\Delta r_1}{\Delta r_2} \approx 0.412 \] ### Final Result: The value of \( \frac{\Delta r_1}{\Delta r_2} \) is approximately **0.412**.
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